Cargando…
(E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline
The title Schiff base compound, C(15)H(14)BrNO(2), adopts an E configuration with respect to the C=N bond. The C and O atoms of the two methoxy substituents lie very close to the dimethoxyphenyl ring plane [maximum deviation = 0.17 (1) Å]. The dihedral angle between the two aromatic rings is 43.69...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968501/ https://www.ncbi.nlm.nih.gov/pubmed/21582212 http://dx.doi.org/10.1107/S1600536809004905 |
_version_ | 1782189895932968960 |
---|---|
author | Khalaji, Aliakbar D. Simpson, Jim |
author_facet | Khalaji, Aliakbar D. Simpson, Jim |
author_sort | Khalaji, Aliakbar D. |
collection | PubMed |
description | The title Schiff base compound, C(15)H(14)BrNO(2), adopts an E configuration with respect to the C=N bond. The C and O atoms of the two methoxy substituents lie very close to the dimethoxyphenyl ring plane [maximum deviation = 0.17 (1) Å]. The dihedral angle between the two aromatic rings is 43.69 (16)°, while the plane through the central C—C=N—C system is inclined at 10.6 (6)° to the dimethoxyphenyl ring and 34.6 (3)° to the bromophenyl ring. In the crystal structure, each molecule is involved in the formation of two inversion-related dimers through weak C—H⋯N and C—H⋯O interactions, respectively. These contacts link the molecules into independent rows parallel to the b axis. |
format | Text |
id | pubmed-2968501 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29685012010-12-30 (E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline Khalaji, Aliakbar D. Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(15)H(14)BrNO(2), adopts an E configuration with respect to the C=N bond. The C and O atoms of the two methoxy substituents lie very close to the dimethoxyphenyl ring plane [maximum deviation = 0.17 (1) Å]. The dihedral angle between the two aromatic rings is 43.69 (16)°, while the plane through the central C—C=N—C system is inclined at 10.6 (6)° to the dimethoxyphenyl ring and 34.6 (3)° to the bromophenyl ring. In the crystal structure, each molecule is involved in the formation of two inversion-related dimers through weak C—H⋯N and C—H⋯O interactions, respectively. These contacts link the molecules into independent rows parallel to the b axis. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968501/ /pubmed/21582212 http://dx.doi.org/10.1107/S1600536809004905 Text en © Khalaji and Simpson 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Khalaji, Aliakbar D. Simpson, Jim (E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline |
title | (E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline |
title_full | (E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline |
title_fullStr | (E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline |
title_full_unstemmed | (E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline |
title_short | (E)-4-Bromo-N-(2,4-dimethoxybenzylidene)aniline |
title_sort | (e)-4-bromo-n-(2,4-dimethoxybenzylidene)aniline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968501/ https://www.ncbi.nlm.nih.gov/pubmed/21582212 http://dx.doi.org/10.1107/S1600536809004905 |
work_keys_str_mv | AT khalajialiakbard e4bromon24dimethoxybenzylideneaniline AT simpsonjim e4bromon24dimethoxybenzylideneaniline |