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(E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline

The title Schiff base compound, C(15)H(14)BrNO(2), adopts an E configuration with respect to the C=N bond. The C and O atoms of the two meth­oxy substituents lie very close to the dimethoxy­phenyl ring plane [maximum deviation = 0.17 (1) Å]. The dihedral angle between the two aromatic rings is 43.69...

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Detalles Bibliográficos
Autores principales: Khalaji, Aliakbar D., Simpson, Jim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968501/
https://www.ncbi.nlm.nih.gov/pubmed/21582212
http://dx.doi.org/10.1107/S1600536809004905
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author Khalaji, Aliakbar D.
Simpson, Jim
author_facet Khalaji, Aliakbar D.
Simpson, Jim
author_sort Khalaji, Aliakbar D.
collection PubMed
description The title Schiff base compound, C(15)H(14)BrNO(2), adopts an E configuration with respect to the C=N bond. The C and O atoms of the two meth­oxy substituents lie very close to the dimethoxy­phenyl ring plane [maximum deviation = 0.17 (1) Å]. The dihedral angle between the two aromatic rings is 43.69 (16)°, while the plane through the central C—C=N—C system is inclined at 10.6 (6)° to the dimethoxy­phenyl ring and 34.6 (3)° to the bromo­phenyl ring. In the crystal structure, each mol­ecule is involved in the formation of two inversion-related dimers through weak C—H⋯N and C—H⋯O inter­actions, respectively. These contacts link the mol­ecules into independent rows parallel to the b axis.
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spelling pubmed-29685012010-12-30 (E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline Khalaji, Aliakbar D. Simpson, Jim Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base compound, C(15)H(14)BrNO(2), adopts an E configuration with respect to the C=N bond. The C and O atoms of the two meth­oxy substituents lie very close to the dimethoxy­phenyl ring plane [maximum deviation = 0.17 (1) Å]. The dihedral angle between the two aromatic rings is 43.69 (16)°, while the plane through the central C—C=N—C system is inclined at 10.6 (6)° to the dimethoxy­phenyl ring and 34.6 (3)° to the bromo­phenyl ring. In the crystal structure, each mol­ecule is involved in the formation of two inversion-related dimers through weak C—H⋯N and C—H⋯O inter­actions, respectively. These contacts link the mol­ecules into independent rows parallel to the b axis. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968501/ /pubmed/21582212 http://dx.doi.org/10.1107/S1600536809004905 Text en © Khalaji and Simpson 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khalaji, Aliakbar D.
Simpson, Jim
(E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline
title (E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline
title_full (E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline
title_fullStr (E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline
title_full_unstemmed (E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline
title_short (E)-4-Bromo-N-(2,4-dimethoxy­benzyl­idene)aniline
title_sort (e)-4-bromo-n-(2,4-dimethoxy­benzyl­idene)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968501/
https://www.ncbi.nlm.nih.gov/pubmed/21582212
http://dx.doi.org/10.1107/S1600536809004905
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