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(E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline

The title compound, C(16)H(18)N(2)O, an N-benzyl­ideneaniline derivative with substituents on both aromatic rings, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules exist in the E configuration. The dihedral angle between the two aromatic rings is 8.20 (5...

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Detalles Bibliográficos
Autores principales: Sundararaman, Leela, Ramu, Hema, Kandaswamy, Ramamurthi, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968506/
https://www.ncbi.nlm.nih.gov/pubmed/21582146
http://dx.doi.org/10.1107/S1600536809003869
Descripción
Sumario:The title compound, C(16)H(18)N(2)O, an N-benzyl­ideneaniline derivative with substituents on both aromatic rings, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules exist in the E configuration. The dihedral angle between the two aromatic rings is 8.20 (5)° for mol­ecule A and 12.52 (6)° for mol­ecule B, and the imino C—N torsion angle (τ) is 7.1 (2)° for mol­ecule A and −14.7 (2)° for mol­ecule B. In the crystal structure, mol­ecules are arranged in stacks which propagate along the a-axis direction. The crystal structure is stabilized by a number of weak C—H⋯π inter­actions.