(E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline

The title compound, C(16)H(18)N(2)O, an N-benzyl­ideneaniline derivative with substituents on both aromatic rings, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules exist in the E configuration. The dihedral angle between the two aromatic rings is 8.20 (5...

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Autores principales: Sundararaman, Leela, Ramu, Hema, Kandaswamy, Ramamurthi, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968506/
https://www.ncbi.nlm.nih.gov/pubmed/21582146
http://dx.doi.org/10.1107/S1600536809003869
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author Sundararaman, Leela
Ramu, Hema
Kandaswamy, Ramamurthi
Stoeckli-Evans, Helen
author_facet Sundararaman, Leela
Ramu, Hema
Kandaswamy, Ramamurthi
Stoeckli-Evans, Helen
author_sort Sundararaman, Leela
collection PubMed
description The title compound, C(16)H(18)N(2)O, an N-benzyl­ideneaniline derivative with substituents on both aromatic rings, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules exist in the E configuration. The dihedral angle between the two aromatic rings is 8.20 (5)° for mol­ecule A and 12.52 (6)° for mol­ecule B, and the imino C—N torsion angle (τ) is 7.1 (2)° for mol­ecule A and −14.7 (2)° for mol­ecule B. In the crystal structure, mol­ecules are arranged in stacks which propagate along the a-axis direction. The crystal structure is stabilized by a number of weak C—H⋯π inter­actions.
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spelling pubmed-29685062010-12-30 (E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline Sundararaman, Leela Ramu, Hema Kandaswamy, Ramamurthi Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(18)N(2)O, an N-benzyl­ideneaniline derivative with substituents on both aromatic rings, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. Both mol­ecules exist in the E configuration. The dihedral angle between the two aromatic rings is 8.20 (5)° for mol­ecule A and 12.52 (6)° for mol­ecule B, and the imino C—N torsion angle (τ) is 7.1 (2)° for mol­ecule A and −14.7 (2)° for mol­ecule B. In the crystal structure, mol­ecules are arranged in stacks which propagate along the a-axis direction. The crystal structure is stabilized by a number of weak C—H⋯π inter­actions. International Union of Crystallography 2009-02-06 /pmc/articles/PMC2968506/ /pubmed/21582146 http://dx.doi.org/10.1107/S1600536809003869 Text en © Sundararaman et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sundararaman, Leela
Ramu, Hema
Kandaswamy, Ramamurthi
Stoeckli-Evans, Helen
(E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline
title (E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline
title_full (E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline
title_fullStr (E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline
title_full_unstemmed (E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline
title_short (E)-4-[(4-Methoxy­phen­yl)imino­meth­yl]-N,N-dimethyl­aniline
title_sort (e)-4-[(4-methoxy­phen­yl)imino­meth­yl]-n,n-dimethyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968506/
https://www.ncbi.nlm.nih.gov/pubmed/21582146
http://dx.doi.org/10.1107/S1600536809003869
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AT kandaswamyramamurthi e44methoxyphenyliminomethylnndimethylaniline
AT stoecklievanshelen e44methoxyphenyliminomethylnndimethylaniline

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