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catena-Poly[bis­[cis-dipyrimidine-trans-dithio­cyanato­iron(II)]-di-μ-pyrimidine-[trans-dithio­cyanato­iron(II)]-di-μ-pyrimidine]

In the crystal structure of the title compound, [Fe(3)(NCS)(6)(C(4)H(4)N(2))(8)](n), each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thio­cyanate anions in a distorted octa­hedral environment. The asymmetric unit consists of one iron cation located on a cryst...

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Detalles Bibliográficos
Autores principales: Wriedt, Mario, Sellmer, Sina, Jess, Inke, Näther, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968508/
https://www.ncbi.nlm.nih.gov/pubmed/21582078
http://dx.doi.org/10.1107/S1600536809005509
Descripción
Sumario:In the crystal structure of the title compound, [Fe(3)(NCS)(6)(C(4)H(4)N(2))(8)](n), each iron(II) cation is coordinated by four N-bonded pyrimidine ligands and two N-bonded thio­cyanate anions in a distorted octa­hedral environment. The asymmetric unit consists of one iron cation located on a crystallographic center of inversion, as well as one iron cation, three thio­cyanate anions and four pyrimidine ligands occupying general positions. The structure consists of square secondary building units (SBUs) with an Fe atom at each corner, which are μ-N (1):N (3)-bridged by the pyrimidine ligands. The SBUs are linked into infinite chains running in the c-axis direction via common opposite corners.