Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate

The title compound, C(23)H(23)BrO(4), is an inter­mediate in the synthesis of fused heterocycles. In the title mol­ecule, the cyclo­hexene ring has a distorted half-chair conformation. The bromo­phenyl ring and the mean plane of the cyclo­hexene ring form a dihedral angle of 13.8 (3)°, whereas the b...

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Detalles Bibliográficos
Autores principales: Badshah, Amir, Hasan, Aurangzeb, Barbarín, Cecilia R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968510/
https://www.ncbi.nlm.nih.gov/pubmed/21582138
http://dx.doi.org/10.1107/S1600536809003523
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author Badshah, Amir
Hasan, Aurangzeb
Barbarín, Cecilia R.
author_facet Badshah, Amir
Hasan, Aurangzeb
Barbarín, Cecilia R.
author_sort Badshah, Amir
collection PubMed
description The title compound, C(23)H(23)BrO(4), is an inter­mediate in the synthesis of fused heterocycles. In the title mol­ecule, the cyclo­hexene ring has a distorted half-chair conformation. The bromo­phenyl ring and the mean plane of the cyclo­hexene ring form a dihedral angle of 13.8 (3)°, whereas the benzene and cyclo­hexene rings are approximately perpendicular [88.44 (17)°]. There are only weak C—H⋯O and C—H⋯π inter­molecular inter­actions.
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spelling pubmed-29685102010-12-30 Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate Badshah, Amir Hasan, Aurangzeb Barbarín, Cecilia R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(23)BrO(4), is an inter­mediate in the synthesis of fused heterocycles. In the title mol­ecule, the cyclo­hexene ring has a distorted half-chair conformation. The bromo­phenyl ring and the mean plane of the cyclo­hexene ring form a dihedral angle of 13.8 (3)°, whereas the benzene and cyclo­hexene rings are approximately perpendicular [88.44 (17)°]. There are only weak C—H⋯O and C—H⋯π inter­molecular inter­actions. International Union of Crystallography 2009-02-06 /pmc/articles/PMC2968510/ /pubmed/21582138 http://dx.doi.org/10.1107/S1600536809003523 Text en © Badshah et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Badshah, Amir
Hasan, Aurangzeb
Barbarín, Cecilia R.
Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate
title Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate
title_full Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate
title_fullStr Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate
title_full_unstemmed Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate
title_short Ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate
title_sort ethyl 4-(4-bromo­phen­yl)-6-(4-ethoxy­phen­yl)-2-oxocyclo­hex-3-enecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968510/
https://www.ncbi.nlm.nih.gov/pubmed/21582138
http://dx.doi.org/10.1107/S1600536809003523
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AT hasanaurangzeb ethyl44bromophenyl64ethoxyphenyl2oxocyclohex3enecarboxylate
AT barbarinceciliar ethyl44bromophenyl64ethoxyphenyl2oxocyclohex3enecarboxylate

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