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Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]

The asymmetric unit of the title compound, {[AgNd(C(6)H(4)NO(2))(2)(C(2)O(4))]·2H(2)O}(n), contains one Nd(III) atom, one Ag(I) atom, one oxalate ligand, two nicotinate ligands and two uncoordinated water mol­ecules. The Nd(III) atom is eight-coordinated in a distorted square-anti­prismatic coordina...

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Detalles Bibliográficos
Autores principales: Nie, Xiao-Yan, Li, Qian-Zhu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968511/
https://www.ncbi.nlm.nih.gov/pubmed/21582099
http://dx.doi.org/10.1107/S1600536809005947
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author Nie, Xiao-Yan
Li, Qian-Zhu
author_facet Nie, Xiao-Yan
Li, Qian-Zhu
author_sort Nie, Xiao-Yan
collection PubMed
description The asymmetric unit of the title compound, {[AgNd(C(6)H(4)NO(2))(2)(C(2)O(4))]·2H(2)O}(n), contains one Nd(III) atom, one Ag(I) atom, one oxalate ligand, two nicotinate ligands and two uncoordinated water mol­ecules. The Nd(III) atom is eight-coordinated in a distorted square-anti­prismatic coordination geometry by four O atoms from two oxalate ligands and four O atoms from four nicotinate ligands. The Ag(I) atom has a T-shaped configuration, defined by two N atoms from two nicotinate ligands and one O atom from one oxalate ligand. The nicotinate and oxalate ligands link the Nd and Ag atoms into a three-dimensional coordination framework. O—H⋯O and O—H⋯N hydrogen bonds donated by water mol­ecules are observed in the crystal.
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spelling pubmed-29685112010-12-30 Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] Nie, Xiao-Yan Li, Qian-Zhu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[AgNd(C(6)H(4)NO(2))(2)(C(2)O(4))]·2H(2)O}(n), contains one Nd(III) atom, one Ag(I) atom, one oxalate ligand, two nicotinate ligands and two uncoordinated water mol­ecules. The Nd(III) atom is eight-coordinated in a distorted square-anti­prismatic coordination geometry by four O atoms from two oxalate ligands and four O atoms from four nicotinate ligands. The Ag(I) atom has a T-shaped configuration, defined by two N atoms from two nicotinate ligands and one O atom from one oxalate ligand. The nicotinate and oxalate ligands link the Nd and Ag atoms into a three-dimensional coordination framework. O—H⋯O and O—H⋯N hydrogen bonds donated by water mol­ecules are observed in the crystal. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968511/ /pubmed/21582099 http://dx.doi.org/10.1107/S1600536809005947 Text en © Nie and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nie, Xiao-Yan
Li, Qian-Zhu
Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]
title Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]
title_full Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]
title_fullStr Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]
title_full_unstemmed Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]
title_short Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]
title_sort poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(iii)silver(i)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968511/
https://www.ncbi.nlm.nih.gov/pubmed/21582099
http://dx.doi.org/10.1107/S1600536809005947
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AT liqianzhu polydim3nicotinatohemim4oxalatohemim2oxalatoneodymiumiiisilveridihydrate