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Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate]
The asymmetric unit of the title compound, {[AgNd(C(6)H(4)NO(2))(2)(C(2)O(4))]·2H(2)O}(n), contains one Nd(III) atom, one Ag(I) atom, one oxalate ligand, two nicotinate ligands and two uncoordinated water molecules. The Nd(III) atom is eight-coordinated in a distorted square-antiprismatic coordina...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968511/ https://www.ncbi.nlm.nih.gov/pubmed/21582099 http://dx.doi.org/10.1107/S1600536809005947 |
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author | Nie, Xiao-Yan Li, Qian-Zhu |
author_facet | Nie, Xiao-Yan Li, Qian-Zhu |
author_sort | Nie, Xiao-Yan |
collection | PubMed |
description | The asymmetric unit of the title compound, {[AgNd(C(6)H(4)NO(2))(2)(C(2)O(4))]·2H(2)O}(n), contains one Nd(III) atom, one Ag(I) atom, one oxalate ligand, two nicotinate ligands and two uncoordinated water molecules. The Nd(III) atom is eight-coordinated in a distorted square-antiprismatic coordination geometry by four O atoms from two oxalate ligands and four O atoms from four nicotinate ligands. The Ag(I) atom has a T-shaped configuration, defined by two N atoms from two nicotinate ligands and one O atom from one oxalate ligand. The nicotinate and oxalate ligands link the Nd and Ag atoms into a three-dimensional coordination framework. O—H⋯O and O—H⋯N hydrogen bonds donated by water molecules are observed in the crystal. |
format | Text |
id | pubmed-2968511 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29685112010-12-30 Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] Nie, Xiao-Yan Li, Qian-Zhu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[AgNd(C(6)H(4)NO(2))(2)(C(2)O(4))]·2H(2)O}(n), contains one Nd(III) atom, one Ag(I) atom, one oxalate ligand, two nicotinate ligands and two uncoordinated water molecules. The Nd(III) atom is eight-coordinated in a distorted square-antiprismatic coordination geometry by four O atoms from two oxalate ligands and four O atoms from four nicotinate ligands. The Ag(I) atom has a T-shaped configuration, defined by two N atoms from two nicotinate ligands and one O atom from one oxalate ligand. The nicotinate and oxalate ligands link the Nd and Ag atoms into a three-dimensional coordination framework. O—H⋯O and O—H⋯N hydrogen bonds donated by water molecules are observed in the crystal. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968511/ /pubmed/21582099 http://dx.doi.org/10.1107/S1600536809005947 Text en © Nie and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Nie, Xiao-Yan Li, Qian-Zhu Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] |
title | Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] |
title_full | Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] |
title_fullStr | Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] |
title_full_unstemmed | Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] |
title_short | Poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(III)silver(I)] dihydrate] |
title_sort | poly[[di-μ(3)-nicotinato-hemi-μ(4)-oxalato-hemi-μ(2)-oxalato-neodymium(iii)silver(i)] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968511/ https://www.ncbi.nlm.nih.gov/pubmed/21582099 http://dx.doi.org/10.1107/S1600536809005947 |
work_keys_str_mv | AT niexiaoyan polydim3nicotinatohemim4oxalatohemim2oxalatoneodymiumiiisilveridihydrate AT liqianzhu polydim3nicotinatohemim4oxalatohemim2oxalatoneodymiumiiisilveridihydrate |