2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide

The title compound, C(12)H(23)PSe, represents the first structure of a phosphine containing the bicyclic 2-phospha­bicyclo­[3.3.1]nonane (VCH) unit. It contains two chiral centres per mol­ecule which can be either R,R- or S,S and crystallizes as a centrosymmetric, racemic micture of the enanti­omers...

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Detalles Bibliográficos
Autores principales: Bungu, Peter N., Otto, Stefanus
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968513/
https://www.ncbi.nlm.nih.gov/pubmed/21582218
http://dx.doi.org/10.1107/S1600536809005492
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author Bungu, Peter N.
Otto, Stefanus
author_facet Bungu, Peter N.
Otto, Stefanus
author_sort Bungu, Peter N.
collection PubMed
description The title compound, C(12)H(23)PSe, represents the first structure of a phosphine containing the bicyclic 2-phospha­bicyclo­[3.3.1]nonane (VCH) unit. It contains two chiral centres per mol­ecule which can be either R,R- or S,S and crystallizes as a centrosymmetric, racemic micture of the enanti­omers. The P—Se bond distance of 2.1360 (16) Å is typical for these compounds. The Tolman cone angle (2.28 Å from P) was calculated as 163°, and the effective cone angle (using the crystallographically determined P—Se bond distance) is 168°.
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spelling pubmed-29685132010-12-30 2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide Bungu, Peter N. Otto, Stefanus Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(23)PSe, represents the first structure of a phosphine containing the bicyclic 2-phospha­bicyclo­[3.3.1]nonane (VCH) unit. It contains two chiral centres per mol­ecule which can be either R,R- or S,S and crystallizes as a centrosymmetric, racemic micture of the enanti­omers. The P—Se bond distance of 2.1360 (16) Å is typical for these compounds. The Tolman cone angle (2.28 Å from P) was calculated as 163°, and the effective cone angle (using the crystallographically determined P—Se bond distance) is 168°. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968513/ /pubmed/21582218 http://dx.doi.org/10.1107/S1600536809005492 Text en © Bungu and Otto 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bungu, Peter N.
Otto, Stefanus
2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide
title 2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide
title_full 2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide
title_fullStr 2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide
title_full_unstemmed 2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide
title_short 2-Isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide
title_sort 2-isobutyl-2-phosphabicyclo­[3.3.1]nonane 2-selenide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968513/
https://www.ncbi.nlm.nih.gov/pubmed/21582218
http://dx.doi.org/10.1107/S1600536809005492
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