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Poly[[tris[μ-2,2′-(butane-1,4-diyldithio)bis(1,3,4-thiadiazole)-κ(2) N (4):N (4′)]copper(II)] bis(perchlorate)]
In the title compound, {[Cu(C(8)H(10)N(4)S(4))(3)](ClO(4))(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2′-(butane-1,4-diyldithio)bis(1,3,4-thiadiazole) ligands in a slightly distorted octahedral geometry. Adjacent Cu(II) at...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968516/ https://www.ncbi.nlm.nih.gov/pubmed/21582085 http://dx.doi.org/10.1107/S1600536809005625 |
Sumario: | In the title compound, {[Cu(C(8)H(10)N(4)S(4))(3)](ClO(4))(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2′-(butane-1,4-diyldithio)bis(1,3,4-thiadiazole) ligands in a slightly distorted octahedral geometry. Adjacent Cu(II) atoms are linked by the bridging bidentate thiadiazole ligands, which are situated about inversion centers. This leads to the formation of a three-dimensional network structure. |
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