Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)]

In the title compound, {[Cu(C(8)H(10)N(4)S(4))(3)](ClO(4))(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole) ligands in a slightly distorted octa­hedral geometry. Adjacent Cu(II) at...

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Detalles Bibliográficos
Autores principales: Hu, Pu-Zhou, Qin, Jian-Hua, Wang, Jian-Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968516/
https://www.ncbi.nlm.nih.gov/pubmed/21582085
http://dx.doi.org/10.1107/S1600536809005625
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author Hu, Pu-Zhou
Qin, Jian-Hua
Wang, Jian-Ge
author_facet Hu, Pu-Zhou
Qin, Jian-Hua
Wang, Jian-Ge
author_sort Hu, Pu-Zhou
collection PubMed
description In the title compound, {[Cu(C(8)H(10)N(4)S(4))(3)](ClO(4))(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole) ligands in a slightly distorted octa­hedral geometry. Adjacent Cu(II) atoms are linked by the bridging bidentate thia­diazole ligands, which are situated about inversion centers. This leads to the formation of a three-dimensional network structure.
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spelling pubmed-29685162010-12-30 Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)] Hu, Pu-Zhou Qin, Jian-Hua Wang, Jian-Ge Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(8)H(10)N(4)S(4))(3)](ClO(4))(2)}(n), the Cu(II) atom is located on a threefold inversion axis coordinated by six N atoms of symmetry-equivalent 2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole) ligands in a slightly distorted octa­hedral geometry. Adjacent Cu(II) atoms are linked by the bridging bidentate thia­diazole ligands, which are situated about inversion centers. This leads to the formation of a three-dimensional network structure. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968516/ /pubmed/21582085 http://dx.doi.org/10.1107/S1600536809005625 Text en © Hu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Pu-Zhou
Qin, Jian-Hua
Wang, Jian-Ge
Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)]
title Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)]
title_full Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)]
title_fullStr Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)]
title_full_unstemmed Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)]
title_short Poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) N (4):N (4′)]copper(II)] bis­(perchlorate)]
title_sort poly[[tris­[μ-2,2′-(butane-1,4-diyl­dithio)bis­(1,3,4-thia­diazole)-κ(2) n (4):n (4′)]copper(ii)] bis­(perchlorate)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968516/
https://www.ncbi.nlm.nih.gov/pubmed/21582085
http://dx.doi.org/10.1107/S1600536809005625
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AT qinjianhua polytrism22butane14diyldithiobis134thiadiazolek2n4n4copperiibisperchlorate
AT wangjiange polytrism22butane14diyldithiobis134thiadiazolek2n4n4copperiibisperchlorate

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