Tetra-μ(2)-oxido-di-μ(4)-peroxido-tetra­kis[diphenyl­anti­mony(V)] chloro­form disolvate

The title compound, [Sb(4)(C(6)H(5))(8)O(4)(O(2))(2)]·2CHCl(3), contains a tetranuclear antimony(V) core, bridged by oxide and peroxide ligands. Two cores form centrosymmetric dimers by intermolecular C—H⋯O contacts. These dimeric units are further connected by chloro­form solvent mol­ecules involve...

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Detalles Bibliográficos
Autores principales: Betz, Richard, Lindner, Christoph, Klüfers, Peter, Mayer, Peter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968518/
https://www.ncbi.nlm.nih.gov/pubmed/21582046
http://dx.doi.org/10.1107/S160053680804419X
Descripción
Sumario:The title compound, [Sb(4)(C(6)H(5))(8)O(4)(O(2))(2)]·2CHCl(3), contains a tetranuclear antimony(V) core, bridged by oxide and peroxide ligands. Two cores form centrosymmetric dimers by intermolecular C—H⋯O contacts. These dimeric units are further connected by chloro­form solvent mol­ecules involved in C—H⋯O and C—H⋯Cl inter­actions into strands along [010]. The five-membered Sb(2)O(3) rings in the Sb(4)O(8) core invariably adopt envelope conformations.

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