Cargando…
Poly[aquabis(μ-benzene-1,2-dicarboxylato)ethanoltetralithium]
In the crystal structure of the title compound [Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O)](n), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxylate groups act as bidentate–bridging ligands producing a two-dimension...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968522/ https://www.ncbi.nlm.nih.gov/pubmed/21582040 http://dx.doi.org/10.1107/S1600536809003390 |
Sumario: | In the crystal structure of the title compound [Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O)](n), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxylate groups act as bidentate–bridging ligands producing a two-dimensional coordination network parallel to the ab plane. The coordination polymer is further stabilized by coordination of water and ethanol molecules by the Li(+) ions. Simultaneously, the water and ethanol molecules are involved in O—H⋯O and C—H⋯π interactions. |
---|