Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]

In the crystal structure of the title compound [Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O)](n), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxyl­ate groups act as bidentate–bridging ligands producing a two-dimension...

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Detalles Bibliográficos
Autores principales: Rodríguez-Cuamatzi, Patricia, Tlahuext, Hugo, Höpfl, Herbert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968522/
https://www.ncbi.nlm.nih.gov/pubmed/21582040
http://dx.doi.org/10.1107/S1600536809003390
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author Rodríguez-Cuamatzi, Patricia
Tlahuext, Hugo
Höpfl, Herbert
author_facet Rodríguez-Cuamatzi, Patricia
Tlahuext, Hugo
Höpfl, Herbert
author_sort Rodríguez-Cuamatzi, Patricia
collection PubMed
description In the crystal structure of the title compound [Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O)](n), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxyl­ate groups act as bidentate–bridging ligands producing a two-dimensional coordination network parallel to the ab plane. The coordination polymer is further stabilized by coordination of water and ethanol mol­ecules by the Li(+) ions. Simultaneously, the water and ethanol mol­ecules are involved in O—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-29685222010-12-30 Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium] Rodríguez-Cuamatzi, Patricia Tlahuext, Hugo Höpfl, Herbert Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound [Li(4)(C(8)H(4)O(4))(2)(C(2)H(5)OH)(H(2)O)](n), there are four crystallographically independent metal centers each of which is coordinated by four O atoms. The benzene-1,2-dicarboxyl­ate groups act as bidentate–bridging ligands producing a two-dimensional coordination network parallel to the ab plane. The coordination polymer is further stabilized by coordination of water and ethanol mol­ecules by the Li(+) ions. Simultaneously, the water and ethanol mol­ecules are involved in O—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968522/ /pubmed/21582040 http://dx.doi.org/10.1107/S1600536809003390 Text en © Rodríguez-Cuamatzi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rodríguez-Cuamatzi, Patricia
Tlahuext, Hugo
Höpfl, Herbert
Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]
title Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]
title_full Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]
title_fullStr Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]
title_full_unstemmed Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]
title_short Poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]
title_sort poly[aqua­bis(μ-benzene-1,2-dicarboxyl­ato)ethano­ltetra­lithium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968522/
https://www.ncbi.nlm.nih.gov/pubmed/21582040
http://dx.doi.org/10.1107/S1600536809003390
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AT hopflherbert polyaquabismbenzene12dicarboxylatoethanoltetralithium

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