rac-N-{6-[Bromo­(hydr­oxy)meth­yl]-2-pyrid­yl}pivalamide

The title compound, C(11)H(15)BrN(2)O(2), contains an amide group which is close to coplanar with the adjacent pyridine ring, the dihedral angle between the planes being 9.0 (5)°. The mol­ecular packing reveals a mutual hydrogen-bond inter­action between centrosymmetrically related hydroxyl O atoms....

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Detalles Bibliográficos
Autores principales: Knight, James C., Saad, Fawaz A., Amoroso, Angelo J., Kariuki, Benson M., Coles, Simon J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968524/
https://www.ncbi.nlm.nih.gov/pubmed/21582295
http://dx.doi.org/10.1107/S1600536809006795
Descripción
Sumario:The title compound, C(11)H(15)BrN(2)O(2), contains an amide group which is close to coplanar with the adjacent pyridine ring, the dihedral angle between the planes being 9.0 (5)°. The mol­ecular packing reveals a mutual hydrogen-bond inter­action between centrosymmetrically related hydroxyl O atoms. Further hydrogen bonding involving O—H⋯Br and N—H⋯Br inter­actions also appears to consolidate the packing.

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