1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate

The aromatic mol­ecule of the title compound, C(20)H(14)N(4)·2C(3)H(7)NO, occupies a special position on an inversion center. The benzimidazole unit (planar to within 0.008 Å) forms a dihedral angle of 9.1 (2)° with the central benzene ring. The benzimidazole H atom participates in a hydrogen bond w...

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Detalles Bibliográficos
Autores principales: Wu, De-Hong, Hu, Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968526/
https://www.ncbi.nlm.nih.gov/pubmed/21582185
http://dx.doi.org/10.1107/S1600536809004759
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author Wu, De-Hong
Hu, Ling
author_facet Wu, De-Hong
Hu, Ling
author_sort Wu, De-Hong
collection PubMed
description The aromatic mol­ecule of the title compound, C(20)H(14)N(4)·2C(3)H(7)NO, occupies a special position on an inversion center. The benzimidazole unit (planar to within 0.008 Å) forms a dihedral angle of 9.1 (2)° with the central benzene ring. The benzimidazole H atom participates in a hydrogen bond with the dimethyl­formamide solvent molecule, thus giving rise to the title 1:2 aggregate. These aggregates are further linked in the crystal structure by aromatic π–π stacking inter­actions [centroid–centroid distance = 6.356 (2) Å].
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spelling pubmed-29685262010-12-30 1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate Wu, De-Hong Hu, Ling Acta Crystallogr Sect E Struct Rep Online Organic Papers The aromatic mol­ecule of the title compound, C(20)H(14)N(4)·2C(3)H(7)NO, occupies a special position on an inversion center. The benzimidazole unit (planar to within 0.008 Å) forms a dihedral angle of 9.1 (2)° with the central benzene ring. The benzimidazole H atom participates in a hydrogen bond with the dimethyl­formamide solvent molecule, thus giving rise to the title 1:2 aggregate. These aggregates are further linked in the crystal structure by aromatic π–π stacking inter­actions [centroid–centroid distance = 6.356 (2) Å]. International Union of Crystallography 2009-02-13 /pmc/articles/PMC2968526/ /pubmed/21582185 http://dx.doi.org/10.1107/S1600536809004759 Text en © Wu and Hu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, De-Hong
Hu, Ling
1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate
title 1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate
title_full 1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate
title_fullStr 1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate
title_full_unstemmed 1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate
title_short 1,4-Bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate
title_sort 1,4-bis(benzimidazol-2-yl)benzene dimethyl­formamide disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968526/
https://www.ncbi.nlm.nih.gov/pubmed/21582185
http://dx.doi.org/10.1107/S1600536809004759
work_keys_str_mv AT wudehong 14bisbenzimidazol2ylbenzenedimethylformamidedisolvate
AT huling 14bisbenzimidazol2ylbenzenedimethylformamidedisolvate

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