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Poly[[[diaqua­cobalt(II)]-bis­[μ(2)-1,1′-(butane-1,4-di­yl)diimidazole-κ(2) N (3):N (3′)]] dinitrate]

In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Co(II) ion lies on an inversion center and is six-coordinated in an octa­hedral environment by four N atoms from four different 1,1′-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol­ecules. The Co(I...

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Detalles Bibliográficos
Autores principales: Su, Yu, He, Chuan, Sun, Zhi-Zhong, Hou, Guang-Feng, Gao, Jin-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968530/
https://www.ncbi.nlm.nih.gov/pubmed/21582089
http://dx.doi.org/10.1107/S1600536809005881
Descripción
Sumario:In the title compound, {[Co(C(10)H(14)N(4))(2)(H(2)O)(2)](NO(3))(2)}(n), the Co(II) ion lies on an inversion center and is six-coordinated in an octa­hedral environment by four N atoms from four different 1,1′-butane-1,4-diyldiimidazole ligands and two O atoms from the two water mol­ecules. The Co(II) atoms are bridged by ligands, generating a two-dimensional (4,4)-network. Adjacent fishnet planes are linked to the nitrate anions via O—H⋯O hydrogen bonds, forming a three-dimensional supra­molecular structure.