2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate

The six-membered cyclo­hexene ring in the title compound, C(17)H(19)Cl(2)NOS(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.716 (3) Å from the plane passing through the other five atoms of the ring (r.m.s. deviation =...

Descripción completa

Detalles Bibliográficos
Autores principales: El Ashry, El Sayed H., Amer, Mohammed R., Shah, M. Raza, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968539/
https://www.ncbi.nlm.nih.gov/pubmed/21582256
http://dx.doi.org/10.1107/S1600536809006199
_version_ 1782189908171948032
author El Ashry, El Sayed H.
Amer, Mohammed R.
Shah, M. Raza
Ng, Seik Weng
author_facet El Ashry, El Sayed H.
Amer, Mohammed R.
Shah, M. Raza
Ng, Seik Weng
author_sort El Ashry, El Sayed H.
collection PubMed
description The six-membered cyclo­hexene ring in the title compound, C(17)H(19)Cl(2)NOS(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.716 (3) Å from the plane passing through the other five atoms of the ring (r.m.s. deviation = 0.072 Å). The mol­ecular conformation is stabilized by an intra­molecular N—H⋯S hydrogen bond. The hydr­oxy group engages in inter­molecular O—H⋯O hydrogen bonding with adjacent acceptor atoms to generate a zigzag chain running along the c axis.
format Text
id pubmed-2968539
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29685392010-12-30 2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate El Ashry, El Sayed H. Amer, Mohammed R. Shah, M. Raza Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The six-membered cyclo­hexene ring in the title compound, C(17)H(19)Cl(2)NOS(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.716 (3) Å from the plane passing through the other five atoms of the ring (r.m.s. deviation = 0.072 Å). The mol­ecular conformation is stabilized by an intra­molecular N—H⋯S hydrogen bond. The hydr­oxy group engages in inter­molecular O—H⋯O hydrogen bonding with adjacent acceptor atoms to generate a zigzag chain running along the c axis. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968539/ /pubmed/21582256 http://dx.doi.org/10.1107/S1600536809006199 Text en © El Ashry et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
El Ashry, El Sayed H.
Amer, Mohammed R.
Shah, M. Raza
Ng, Seik Weng
2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate
title 2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate
title_full 2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate
title_fullStr 2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate
title_full_unstemmed 2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate
title_short 2-Hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate
title_sort 2-hydroxy­ethyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-ene­carbo­dithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968539/
https://www.ncbi.nlm.nih.gov/pubmed/21582256
http://dx.doi.org/10.1107/S1600536809006199
work_keys_str_mv AT elashryelsayedh 2hydroxyethyl224dichloroanilino44dimethyl6oxocyclohex1enecarbodithioate
AT amermohammedr 2hydroxyethyl224dichloroanilino44dimethyl6oxocyclohex1enecarbodithioate
AT shahmraza 2hydroxyethyl224dichloroanilino44dimethyl6oxocyclohex1enecarbodithioate
AT ngseikweng 2hydroxyethyl224dichloroanilino44dimethyl6oxocyclohex1enecarbodithioate

Ejemplares similares