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trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II)

In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis­(2-methoxy­phen­yl)triazene ligands and by the O atoms of two methanol mol­ecules. The distorted octa­hedral coordination geometry of the Cd atom has t...

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Detalles Bibliográficos
Autores principales: Rofouei, Mohammad Kazem, Melardi, Mohammad Reza, Khalili Ghaydari, Hamid Reza, Barkhi, Mohammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968540/
https://www.ncbi.nlm.nih.gov/pubmed/21582114
http://dx.doi.org/10.1107/S160053680900676X
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author Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Khalili Ghaydari, Hamid Reza
Barkhi, Mohammad
author_facet Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Khalili Ghaydari, Hamid Reza
Barkhi, Mohammad
author_sort Rofouei, Mohammad Kazem
collection PubMed
description In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis­(2-methoxy­phen­yl)triazene ligands and by the O atoms of two methanol mol­ecules. The distorted octa­hedral coordination geometry of the Cd atom has two N and two O atoms in the equatorial plane, and two O atoms in axial positions. The complex is stabilized by intra­molecular O—H⋯O and O—H⋯N hydrogen bonds. In the crystal structure the complexes are linked into chains via inter­molecular C—H⋯π stacking inter­actions. One of the methanol C atoms is disordered with ouccupancies of 0.7:0.3.
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spelling pubmed-29685402010-12-30 trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II) Rofouei, Mohammad Kazem Melardi, Mohammad Reza Khalili Ghaydari, Hamid Reza Barkhi, Mohammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis­(2-methoxy­phen­yl)triazene ligands and by the O atoms of two methanol mol­ecules. The distorted octa­hedral coordination geometry of the Cd atom has two N and two O atoms in the equatorial plane, and two O atoms in axial positions. The complex is stabilized by intra­molecular O—H⋯O and O—H⋯N hydrogen bonds. In the crystal structure the complexes are linked into chains via inter­molecular C—H⋯π stacking inter­actions. One of the methanol C atoms is disordered with ouccupancies of 0.7:0.3. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968540/ /pubmed/21582114 http://dx.doi.org/10.1107/S160053680900676X Text en © Rofouei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rofouei, Mohammad Kazem
Melardi, Mohammad Reza
Khalili Ghaydari, Hamid Reza
Barkhi, Mohammad
trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II)
title trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II)
title_full trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II)
title_fullStr trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II)
title_full_unstemmed trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II)
title_short trans-Bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(II)
title_sort trans-bis[1,3-bis­(2-methoxy­phen­yl)triazenido]dimethano­lcadmium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968540/
https://www.ncbi.nlm.nih.gov/pubmed/21582114
http://dx.doi.org/10.1107/S160053680900676X
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