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trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II)
In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis(2-methoxyphenyl)triazene ligands and by the O atoms of two methanol molecules. The distorted octahedral coordination geometry of the Cd atom has t...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968540/ https://www.ncbi.nlm.nih.gov/pubmed/21582114 http://dx.doi.org/10.1107/S160053680900676X |
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author | Rofouei, Mohammad Kazem Melardi, Mohammad Reza Khalili Ghaydari, Hamid Reza Barkhi, Mohammad |
author_facet | Rofouei, Mohammad Kazem Melardi, Mohammad Reza Khalili Ghaydari, Hamid Reza Barkhi, Mohammad |
author_sort | Rofouei, Mohammad Kazem |
collection | PubMed |
description | In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis(2-methoxyphenyl)triazene ligands and by the O atoms of two methanol molecules. The distorted octahedral coordination geometry of the Cd atom has two N and two O atoms in the equatorial plane, and two O atoms in axial positions. The complex is stabilized by intramolecular O—H⋯O and O—H⋯N hydrogen bonds. In the crystal structure the complexes are linked into chains via intermolecular C—H⋯π stacking interactions. One of the methanol C atoms is disordered with ouccupancies of 0.7:0.3. |
format | Text |
id | pubmed-2968540 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29685402010-12-30 trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II) Rofouei, Mohammad Kazem Melardi, Mohammad Reza Khalili Ghaydari, Hamid Reza Barkhi, Mohammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(14)H(14)N(3)O(2))(2)(CH(3)OH)(2)], each cadmium(II) center is six-coordinated by an N atom and an O atom of two 1,3-bis(2-methoxyphenyl)triazene ligands and by the O atoms of two methanol molecules. The distorted octahedral coordination geometry of the Cd atom has two N and two O atoms in the equatorial plane, and two O atoms in axial positions. The complex is stabilized by intramolecular O—H⋯O and O—H⋯N hydrogen bonds. In the crystal structure the complexes are linked into chains via intermolecular C—H⋯π stacking interactions. One of the methanol C atoms is disordered with ouccupancies of 0.7:0.3. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968540/ /pubmed/21582114 http://dx.doi.org/10.1107/S160053680900676X Text en © Rofouei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rofouei, Mohammad Kazem Melardi, Mohammad Reza Khalili Ghaydari, Hamid Reza Barkhi, Mohammad trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II) |
title |
trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II) |
title_full |
trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II) |
title_fullStr |
trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II) |
title_full_unstemmed |
trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II) |
title_short |
trans-Bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(II) |
title_sort | trans-bis[1,3-bis(2-methoxyphenyl)triazenido]dimethanolcadmium(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968540/ https://www.ncbi.nlm.nih.gov/pubmed/21582114 http://dx.doi.org/10.1107/S160053680900676X |
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