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Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate

In the title compound, (C(5)H(7)N(2))(6)[V(10)O(28)]·2H(2)O, the [V(10)O(28)](6−) anion is generated by crystallographic inversion symmetry and each of the five vanadium centres adopts a distorted VO(6) octa­hedral geometry. In the crystal structure, a network of N—H⋯O, N—H⋯(O,O) and O—H⋯O hydrogen...

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Detalles Bibliográficos
Autores principales: Yuan, Caixia, Lu, Liping, Zhu, Miaoli, Ma, Qi, Wu, Yanbo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968550/
https://www.ncbi.nlm.nih.gov/pubmed/21582056
http://dx.doi.org/10.1107/S1600536809004334
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author Yuan, Caixia
Lu, Liping
Zhu, Miaoli
Ma, Qi
Wu, Yanbo
author_facet Yuan, Caixia
Lu, Liping
Zhu, Miaoli
Ma, Qi
Wu, Yanbo
author_sort Yuan, Caixia
collection PubMed
description In the title compound, (C(5)H(7)N(2))(6)[V(10)O(28)]·2H(2)O, the [V(10)O(28)](6−) anion is generated by crystallographic inversion symmetry and each of the five vanadium centres adopts a distorted VO(6) octa­hedral geometry. In the crystal structure, a network of N—H⋯O, N—H⋯(O,O) and O—H⋯O hydrogen bonds helps to establish the packing.
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spelling pubmed-29685502010-12-30 Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate Yuan, Caixia Lu, Liping Zhu, Miaoli Ma, Qi Wu, Yanbo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(5)H(7)N(2))(6)[V(10)O(28)]·2H(2)O, the [V(10)O(28)](6−) anion is generated by crystallographic inversion symmetry and each of the five vanadium centres adopts a distorted VO(6) octa­hedral geometry. In the crystal structure, a network of N—H⋯O, N—H⋯(O,O) and O—H⋯O hydrogen bonds helps to establish the packing. International Union of Crystallography 2009-02-13 /pmc/articles/PMC2968550/ /pubmed/21582056 http://dx.doi.org/10.1107/S1600536809004334 Text en © Yuan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuan, Caixia
Lu, Liping
Zhu, Miaoli
Ma, Qi
Wu, Yanbo
Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate
title Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate
title_full Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate
title_fullStr Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate
title_full_unstemmed Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate
title_short Hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(V) dihydrate
title_sort hexakis(2-amino­pyridinium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadium(v) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968550/
https://www.ncbi.nlm.nih.gov/pubmed/21582056
http://dx.doi.org/10.1107/S1600536809004334
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