Cargando…

[1-(3-Nitro­phen­yl)-2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazin-3-ylidine]malonaldehyde

The oxazine ring in the title compound, C(21)H(14)N(2)O(5), adopts a flattened boat conformation. The nitro­phenyl ring and the naphthalene ring system enclose a dihedral angle of 89.2 (1)°. An intra­molecular hydrogen bond is formed between the NH group and one of the adjacent carbonyl O atoms. In...

Descripción completa

Detalles Bibliográficos
Autores principales: NizamMohideen, M., SubbiahPandi, A., Selvam, N. Panneer, Perumal, P. T., Damodiran, M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968553/
https://www.ncbi.nlm.nih.gov/pubmed/21582237
http://dx.doi.org/10.1107/S1600536809006023
Descripción
Sumario:The oxazine ring in the title compound, C(21)H(14)N(2)O(5), adopts a flattened boat conformation. The nitro­phenyl ring and the naphthalene ring system enclose a dihedral angle of 89.2 (1)°. An intra­molecular hydrogen bond is formed between the NH group and one of the adjacent carbonyl O atoms. In addition, the NH group forms an inter­molecular hydrogen bond to a symmetry equivalent of this carbonyl O atom, connecting the mol­ecules into centrosymmetric dimers. The structure also contains C—H⋯O inter­molecular inter­actions.