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Propyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate
In the title compound, C(14)H(15)BrO(4)S, the S atom has a distorted trigonal–pyramidal coordination. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The molecules form slightly slipped π-stacked inversion-symmetric d...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968554/ https://www.ncbi.nlm.nih.gov/pubmed/21582183 http://dx.doi.org/10.1107/S160053680900453X |
Sumario: | In the title compound, C(14)H(15)BrO(4)S, the S atom has a distorted trigonal–pyramidal coordination. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The molecules form slightly slipped π-stacked inversion-symmetric dimers by intermolecular aromatic π–π interactions, with a centroid-to-centroid distance of 3.695 (4) Å between the benzene rings of neighbouring molecules. The crystal packing is further stabilized by intermolecular C—H⋯π interactions between the methylene H atoms of the propyl group towards the benzene and furan rings of neighbouring molecules, respectively. Additionally, the crystal structure exhibits weak intermolecular C—H⋯O hydrogen bonds. |
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