Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate

In the title compound, [Al(3)LaCl(12)(C(12)H(18))]·C(6)H(6), all mol­ecules are located on a mirror plane. Three chloridoaluminate groups and a hexa­methyl­benzene mol­ecule are bound to the central lanthanum(III) ion, forming a distorted penta­gonal bipyramid with the η(6)-coordinated arene located...

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Autores principales: Filatov, Alexander S., Gifford, Sarah N., Kumar, D. Krishna, Petrukhina, Marina A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968558/
https://www.ncbi.nlm.nih.gov/pubmed/21582071
http://dx.doi.org/10.1107/S1600536809004899
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author Filatov, Alexander S.
Gifford, Sarah N.
Kumar, D. Krishna
Petrukhina, Marina A.
author_facet Filatov, Alexander S.
Gifford, Sarah N.
Kumar, D. Krishna
Petrukhina, Marina A.
author_sort Filatov, Alexander S.
collection PubMed
description In the title compound, [Al(3)LaCl(12)(C(12)H(18))]·C(6)H(6), all mol­ecules are located on a mirror plane. Three chloridoaluminate groups and a hexa­methyl­benzene mol­ecule are bound to the central lanthanum(III) ion, forming a distorted penta­gonal bipyramid with the η(6)-coordinated arene located at the apical position. The hexa­methyl­benzene ligand disordered between two orientations in a 1:1 ratio is also involved in parallel-slipped π–π stacking inter­molecular inter­actions with a benzene solvent mol­ecule [centroid–centroid distance 3.612 (4) Å].
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spelling pubmed-29685582010-12-30 Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate Filatov, Alexander S. Gifford, Sarah N. Kumar, D. Krishna Petrukhina, Marina A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Al(3)LaCl(12)(C(12)H(18))]·C(6)H(6), all mol­ecules are located on a mirror plane. Three chloridoaluminate groups and a hexa­methyl­benzene mol­ecule are bound to the central lanthanum(III) ion, forming a distorted penta­gonal bipyramid with the η(6)-coordinated arene located at the apical position. The hexa­methyl­benzene ligand disordered between two orientations in a 1:1 ratio is also involved in parallel-slipped π–π stacking inter­molecular inter­actions with a benzene solvent mol­ecule [centroid–centroid distance 3.612 (4) Å]. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968558/ /pubmed/21582071 http://dx.doi.org/10.1107/S1600536809004899 Text en © Filatov et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Filatov, Alexander S.
Gifford, Sarah N.
Kumar, D. Krishna
Petrukhina, Marina A.
Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate
title Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate
title_full Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate
title_fullStr Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate
title_full_unstemmed Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate
title_short Hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(III)lanthanum(III) benzene solvate
title_sort hexa-μ-chlorido-hexa­chlorido(η(6)-hexa­methyl­benzene)trialuminium(iii)lanthanum(iii) benzene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968558/
https://www.ncbi.nlm.nih.gov/pubmed/21582071
http://dx.doi.org/10.1107/S1600536809004899
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AT giffordsarahn hexamchloridohexachloridoē6hexamethylbenzenetrialuminiumiiilanthanumiiibenzenesolvate
AT kumardkrishna hexamchloridohexachloridoē6hexamethylbenzenetrialuminiumiiilanthanumiiibenzenesolvate
AT petrukhinamarinaa hexamchloridohexachloridoē6hexamethylbenzenetrialuminiumiiilanthanumiiibenzenesolvate

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