Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II)

In the title mononuclear complex, [Ni(C(8)H(7)O(3))(2)(C(3)H(4)N(2))(2)], the Ni(II) atom, lying on a twofold rotation axis, is coordinated by four carboxyl­ate O atoms from two bidentate 3-hydroxy­phenylacetato ligands and two N atoms from two imidazole mol­ecules in a distorted octa­hedral geometr...

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Detalles Bibliográficos
Autores principales: Nie, Xiao-Yan, Li, Qian-Zhu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968559/
https://www.ncbi.nlm.nih.gov/pubmed/21582100
http://dx.doi.org/10.1107/S1600536809005960
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author Nie, Xiao-Yan
Li, Qian-Zhu
author_facet Nie, Xiao-Yan
Li, Qian-Zhu
author_sort Nie, Xiao-Yan
collection PubMed
description In the title mononuclear complex, [Ni(C(8)H(7)O(3))(2)(C(3)H(4)N(2))(2)], the Ni(II) atom, lying on a twofold rotation axis, is coordinated by four carboxyl­ate O atoms from two bidentate 3-hydroxy­phenylacetato ligands and two N atoms from two imidazole mol­ecules in a distorted octa­hedral geometry. A three-dimensional network is formed via inter­molecular O—H⋯O and N—H⋯O hydrogen bonds and π–π stacking inter­actions between the imidazole and benzene rings of neighboring mol­ecules [centroid–centroid distance = 3.856 (2) Å].
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spelling pubmed-29685592010-12-30 Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II) Nie, Xiao-Yan Li, Qian-Zhu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title mononuclear complex, [Ni(C(8)H(7)O(3))(2)(C(3)H(4)N(2))(2)], the Ni(II) atom, lying on a twofold rotation axis, is coordinated by four carboxyl­ate O atoms from two bidentate 3-hydroxy­phenylacetato ligands and two N atoms from two imidazole mol­ecules in a distorted octa­hedral geometry. A three-dimensional network is formed via inter­molecular O—H⋯O and N—H⋯O hydrogen bonds and π–π stacking inter­actions between the imidazole and benzene rings of neighboring mol­ecules [centroid–centroid distance = 3.856 (2) Å]. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968559/ /pubmed/21582100 http://dx.doi.org/10.1107/S1600536809005960 Text en © Nie and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nie, Xiao-Yan
Li, Qian-Zhu
Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II)
title Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II)
title_full Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II)
title_fullStr Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II)
title_full_unstemmed Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II)
title_short Bis(3-hydroxy­phenyl­acetato-κ(2) O,O′)bis­(1H-imidazole-κN (3))nickel(II)
title_sort bis(3-hydroxy­phenyl­acetato-κ(2) o,o′)bis­(1h-imidazole-κn (3))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968559/
https://www.ncbi.nlm.nih.gov/pubmed/21582100
http://dx.doi.org/10.1107/S1600536809005960
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