1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane]

In the title compound, C(14)H(15)NO(2), the hydrogenated six-membered ring of the carbazole unit adopts a half-chair conformation and the dioxolane ring points to one side of the carbazole plane. Neighbouring mol­ecules form edge-to-face inter­actions in which the NH group is directed towards an adj...

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Detalles Bibliográficos
Autores principales: Bjerrum, Janni Vester, Ulven, Trond, Bond, Andrew D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968561/
https://www.ncbi.nlm.nih.gov/pubmed/21582234
http://dx.doi.org/10.1107/S1600536809005558
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author Bjerrum, Janni Vester
Ulven, Trond
Bond, Andrew D.
author_facet Bjerrum, Janni Vester
Ulven, Trond
Bond, Andrew D.
author_sort Bjerrum, Janni Vester
collection PubMed
description In the title compound, C(14)H(15)NO(2), the hydrogenated six-membered ring of the carbazole unit adopts a half-chair conformation and the dioxolane ring points to one side of the carbazole plane. Neighbouring mol­ecules form edge-to-face inter­actions in which the NH group is directed towards an adjacent carbazole unit, with a shortest H⋯C contact of 2.72 Å. These inter­actions arrange the mol­ecules into one-dimensional herringbone-type motifs, which pack so that the methyl­ene groups of the dioxolane ring lie over the face of a neighbouring carbazole unit with a shortest H⋯C contact of 2.85 Å.
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spelling pubmed-29685612010-12-30 1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane] Bjerrum, Janni Vester Ulven, Trond Bond, Andrew D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(15)NO(2), the hydrogenated six-membered ring of the carbazole unit adopts a half-chair conformation and the dioxolane ring points to one side of the carbazole plane. Neighbouring mol­ecules form edge-to-face inter­actions in which the NH group is directed towards an adjacent carbazole unit, with a shortest H⋯C contact of 2.72 Å. These inter­actions arrange the mol­ecules into one-dimensional herringbone-type motifs, which pack so that the methyl­ene groups of the dioxolane ring lie over the face of a neighbouring carbazole unit with a shortest H⋯C contact of 2.85 Å. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968561/ /pubmed/21582234 http://dx.doi.org/10.1107/S1600536809005558 Text en © Bjerrum et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bjerrum, Janni Vester
Ulven, Trond
Bond, Andrew D.
1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane]
title 1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane]
title_full 1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane]
title_fullStr 1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane]
title_full_unstemmed 1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane]
title_short 1,2-Di­hydro­spiro­[carbazole-3(4H),2′-[1,3]dioxolane]
title_sort 1,2-di­hydro­spiro­[carbazole-3(4h),2′-[1,3]dioxolane]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968561/
https://www.ncbi.nlm.nih.gov/pubmed/21582234
http://dx.doi.org/10.1107/S1600536809005558
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