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Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-formylbenzoato-κO)nickel(II)
In the title centrosymmetric mononuclear Ni(II) compound, [Ni(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the central Ni(II) atom is coordinated by two O atoms from two 4-formylbenzoate (FOB) ligands, two O atoms from two water molecules and two N atoms from two diethylnicotinamide (DENA) li...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968564/ https://www.ncbi.nlm.nih.gov/pubmed/21582098 http://dx.doi.org/10.1107/S1600536809006345 |
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author | Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Sertçelik, Mustafa |
collection | PubMed |
description | In the title centrosymmetric mononuclear Ni(II) compound, [Ni(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the central Ni(II) atom is coordinated by two O atoms from two 4-formylbenzoate (FOB) ligands, two O atoms from two water molecules and two N atoms from two diethylnicotinamide (DENA) ligands. The coordination geometry is slightly distorted octahedral, with four O atoms in the equatorial plane and two N atoms in axial positions. Intramolecular O—H⋯O hydrogen bonds are observed. In the crystal structure, molecules are linked into chains along the a axis by intermolecular O—H⋯O hydrogen bonds. The structure is further stabilized by π–π interactions between the pyridine rings of DENA units, with a centroid–centroid distance of 3.668 (2) Å. |
format | Text |
id | pubmed-2968564 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29685642010-12-30 Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-formylbenzoato-κO)nickel(II) Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric mononuclear Ni(II) compound, [Ni(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the central Ni(II) atom is coordinated by two O atoms from two 4-formylbenzoate (FOB) ligands, two O atoms from two water molecules and two N atoms from two diethylnicotinamide (DENA) ligands. The coordination geometry is slightly distorted octahedral, with four O atoms in the equatorial plane and two N atoms in axial positions. Intramolecular O—H⋯O hydrogen bonds are observed. In the crystal structure, molecules are linked into chains along the a axis by intermolecular O—H⋯O hydrogen bonds. The structure is further stabilized by π–π interactions between the pyridine rings of DENA units, with a centroid–centroid distance of 3.668 (2) Å. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968564/ /pubmed/21582098 http://dx.doi.org/10.1107/S1600536809006345 Text en © Sertçelik et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer Diaquabis(N,N-diethylnicotinamide-κN (1))bis(4-formylbenzoato-κO)nickel(II) |
title | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO)nickel(II) |
title_full | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO)nickel(II) |
title_fullStr | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO)nickel(II) |
title_full_unstemmed | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO)nickel(II) |
title_short | Diaquabis(N,N-diethylnicotinamide-κN
(1))bis(4-formylbenzoato-κO)nickel(II) |
title_sort | diaquabis(n,n-diethylnicotinamide-κn
(1))bis(4-formylbenzoato-κo)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968564/ https://www.ncbi.nlm.nih.gov/pubmed/21582098 http://dx.doi.org/10.1107/S1600536809006345 |
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