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Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II)

In the title centrosymmetric mononuclear Ni(II) compound, [Ni(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the central Ni(II) atom is coordinated by two O atoms from two 4-formyl­benzoate (FOB) ligands, two O atoms from two water mol­ecules and two N atoms from two diethyl­nicotinamide (DENA) li...

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Autores principales: Sertçelik, Mustafa, Tercan, Barış, Şahin, Ertan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968564/
https://www.ncbi.nlm.nih.gov/pubmed/21582098
http://dx.doi.org/10.1107/S1600536809006345
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author Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Sertçelik, Mustafa
collection PubMed
description In the title centrosymmetric mononuclear Ni(II) compound, [Ni(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the central Ni(II) atom is coordinated by two O atoms from two 4-formyl­benzoate (FOB) ligands, two O atoms from two water mol­ecules and two N atoms from two diethyl­nicotinamide (DENA) ligands. The coordination geometry is slightly distorted octa­hedral, with four O atoms in the equatorial plane and two N atoms in axial positions. Intra­molecular O—H⋯O hydrogen bonds are observed. In the crystal structure, mol­ecules are linked into chains along the a axis by inter­molecular O—H⋯O hydrogen bonds. The structure is further stabilized by π–π inter­actions between the pyridine rings of DENA units, with a centroid–centroid distance of 3.668 (2) Å.
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spelling pubmed-29685642010-12-30 Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II) Sertçelik, Mustafa Tercan, Barış Şahin, Ertan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric mononuclear Ni(II) compound, [Ni(C(8)H(5)O(3))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], the central Ni(II) atom is coordinated by two O atoms from two 4-formyl­benzoate (FOB) ligands, two O atoms from two water mol­ecules and two N atoms from two diethyl­nicotinamide (DENA) ligands. The coordination geometry is slightly distorted octa­hedral, with four O atoms in the equatorial plane and two N atoms in axial positions. Intra­molecular O—H⋯O hydrogen bonds are observed. In the crystal structure, mol­ecules are linked into chains along the a axis by inter­molecular O—H⋯O hydrogen bonds. The structure is further stabilized by π–π inter­actions between the pyridine rings of DENA units, with a centroid–centroid distance of 3.668 (2) Å. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968564/ /pubmed/21582098 http://dx.doi.org/10.1107/S1600536809006345 Text en © Sertçelik et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sertçelik, Mustafa
Tercan, Barış
Şahin, Ertan
Necefoğlu, Hacali
Hökelek, Tuncer
Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II)
title Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II)
title_full Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II)
title_fullStr Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II)
title_full_unstemmed Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II)
title_short Diaqua­bis(N,N-diethyl­nicotinamide-κN (1))bis­(4-formyl­benzoato-κO)nickel(II)
title_sort diaqua­bis(n,n-diethyl­nicotinamide-κn (1))bis­(4-formyl­benzoato-κo)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968564/
https://www.ncbi.nlm.nih.gov/pubmed/21582098
http://dx.doi.org/10.1107/S1600536809006345
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