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2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none

In the mol­ecule of the title compound, C(23)H(29)NO, the cyclo­hexa­none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl­anilino)(phen­yl)meth­yl] portion of the mol­ecule is in an equatorial po...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Rai, Sankappa, Shetty, Prakash, Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968565/
https://www.ncbi.nlm.nih.gov/pubmed/21582199
http://dx.doi.org/10.1107/S1600536809004954
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M.
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M.
author_sort Fun, Hoong-Kun
collection PubMed
description In the mol­ecule of the title compound, C(23)H(29)NO, the cyclo­hexa­none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl­anilino)(phen­yl)meth­yl] portion of the mol­ecule is in an equatorial position on the cyclo­hexa­none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol­ecules are linked by N—H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C—H⋯O and C—H⋯π inter­actions.
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spelling pubmed-29685652010-12-30 2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none Fun, Hoong-Kun Chantrapromma, Suchada Rai, Sankappa Shetty, Prakash Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(23)H(29)NO, the cyclo­hexa­none ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butyl­anilino)(phen­yl)meth­yl] portion of the mol­ecule is in an equatorial position on the cyclo­hexa­none ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, mol­ecules are linked by N—H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C—H⋯O and C—H⋯π inter­actions. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968565/ /pubmed/21582199 http://dx.doi.org/10.1107/S1600536809004954 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M.
2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none
title 2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none
title_full 2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none
title_fullStr 2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none
title_full_unstemmed 2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none
title_short 2-[(4-tert-Butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none
title_sort 2-[(4-tert-butyl­anilino)(phen­yl)meth­yl]cyclo­hexa­none
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968565/
https://www.ncbi.nlm.nih.gov/pubmed/21582199
http://dx.doi.org/10.1107/S1600536809004954
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