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2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone
In the molecule of the title compound, C(23)H(29)NO, the cyclohexanone ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butylanilino)(phenyl)methyl] portion of the molecule is in an equatorial po...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968565/ https://www.ncbi.nlm.nih.gov/pubmed/21582199 http://dx.doi.org/10.1107/S1600536809004954 |
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author | Fun, Hoong-Kun Chantrapromma, Suchada Rai, Sankappa Shetty, Prakash Isloor, Arun M. |
author_facet | Fun, Hoong-Kun Chantrapromma, Suchada Rai, Sankappa Shetty, Prakash Isloor, Arun M. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the molecule of the title compound, C(23)H(29)NO, the cyclohexanone ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butylanilino)(phenyl)methyl] portion of the molecule is in an equatorial position on the cyclohexanone ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, molecules are linked by N—H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C—H⋯O and C—H⋯π interactions. |
format | Text |
id | pubmed-2968565 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29685652010-12-30 2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone Fun, Hoong-Kun Chantrapromma, Suchada Rai, Sankappa Shetty, Prakash Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(23)H(29)NO, the cyclohexanone ring has been distorted from the standard chair conformation by the ketone group such that part of the ring is almost flat. The remaining [(4-tert-butylanilino)(phenyl)methyl] portion of the molecule is in an equatorial position on the cyclohexanone ring. The dihedral angle between the two benzene rings is 81.52 (8)°. In the crystal packing, molecules are linked by N—H⋯O hydrogen bonds into infinite one-dimensional chains along the a axis and these chains are stacked down the c axis. The crystal structure is further stabilized by weak C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968565/ /pubmed/21582199 http://dx.doi.org/10.1107/S1600536809004954 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chantrapromma, Suchada Rai, Sankappa Shetty, Prakash Isloor, Arun M. 2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone |
title | 2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone |
title_full | 2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone |
title_fullStr | 2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone |
title_full_unstemmed | 2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone |
title_short | 2-[(4-tert-Butylanilino)(phenyl)methyl]cyclohexanone |
title_sort | 2-[(4-tert-butylanilino)(phenyl)methyl]cyclohexanone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968565/ https://www.ncbi.nlm.nih.gov/pubmed/21582199 http://dx.doi.org/10.1107/S1600536809004954 |
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