(Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime

The title compound, C(19)H(25)NO(6), is a Z diastereomer in which the phenyl ring of the 3-benzyl­oxime substituent and the 5,6-O-isopropyl­idene acetal are both located on the Si-face of the C=N double bond. Inter­molecular C—H⋯O inter­actions result in helical chains along the b axis of the monocl...

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Detalles Bibliográficos
Autores principales: Burkhardt, Anja, Eriksson, Lars, Widmalm, Göran, Cumpstey, Ian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968566/
https://www.ncbi.nlm.nih.gov/pubmed/21582282
http://dx.doi.org/10.1107/S1600536809006333
Descripción
Sumario:The title compound, C(19)H(25)NO(6), is a Z diastereomer in which the phenyl ring of the 3-benzyl­oxime substituent and the 5,6-O-isopropyl­idene acetal are both located on the Si-face of the C=N double bond. Inter­molecular C—H⋯O inter­actions result in helical chains along the b axis of the monoclinic unit cell.

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