(Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime

The title compound, C(19)H(25)NO(6), is a Z diastereomer in which the phenyl ring of the 3-benzyl­oxime substituent and the 5,6-O-isopropyl­idene acetal are both located on the Si-face of the C=N double bond. Inter­molecular C—H⋯O inter­actions result in helical chains along the b axis of the monocl...

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Detalles Bibliográficos
Autores principales: Burkhardt, Anja, Eriksson, Lars, Widmalm, Göran, Cumpstey, Ian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968566/
https://www.ncbi.nlm.nih.gov/pubmed/21582282
http://dx.doi.org/10.1107/S1600536809006333
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author Burkhardt, Anja
Eriksson, Lars
Widmalm, Göran
Cumpstey, Ian
author_facet Burkhardt, Anja
Eriksson, Lars
Widmalm, Göran
Cumpstey, Ian
author_sort Burkhardt, Anja
collection PubMed
description The title compound, C(19)H(25)NO(6), is a Z diastereomer in which the phenyl ring of the 3-benzyl­oxime substituent and the 5,6-O-isopropyl­idene acetal are both located on the Si-face of the C=N double bond. Inter­molecular C—H⋯O inter­actions result in helical chains along the b axis of the monoclinic unit cell.
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spelling pubmed-29685662010-12-30 (Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime Burkhardt, Anja Eriksson, Lars Widmalm, Göran Cumpstey, Ian Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(25)NO(6), is a Z diastereomer in which the phenyl ring of the 3-benzyl­oxime substituent and the 5,6-O-isopropyl­idene acetal are both located on the Si-face of the C=N double bond. Inter­molecular C—H⋯O inter­actions result in helical chains along the b axis of the monoclinic unit cell. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968566/ /pubmed/21582282 http://dx.doi.org/10.1107/S1600536809006333 Text en © Burkhardt et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Burkhardt, Anja
Eriksson, Lars
Widmalm, Göran
Cumpstey, Ian
(Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime
title (Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime
title_full (Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime
title_fullStr (Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime
title_full_unstemmed (Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime
title_short (Z)-1,2:5,6-Di-O-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose O-benzyl­oxime
title_sort (z)-1,2:5,6-di-o-isopropyl­idene-α-d-ribo-hexofuranos-3-ulose o-benzyl­oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968566/
https://www.ncbi.nlm.nih.gov/pubmed/21582282
http://dx.doi.org/10.1107/S1600536809006333
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