4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one

The stabilized conformation of the title compound, C(36)H(25)NO(3), 4-(9-anthryl)-1-(2-methoxyphenyl)-spiro[azetid­in-3,9′-xanthen]-2-one, may be compared with that of the isomeric compound 4-(9-anthr­yl)-1-(4-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one. In the title isomer, the meth­oxy gro...

Descripción completa

Detalles Bibliográficos
Autores principales: Yalçın, Şerife Pınar, Akkurt, Mehmet, Jarrahpour, Aliasghar, Ebrahimi, Edris, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968572/
https://www.ncbi.nlm.nih.gov/pubmed/21582278
http://dx.doi.org/10.1107/S1600536809005200
_version_ 1782189918716428288
author Yalçın, Şerife Pınar
Akkurt, Mehmet
Jarrahpour, Aliasghar
Ebrahimi, Edris
Büyükgüngör, Orhan
author_facet Yalçın, Şerife Pınar
Akkurt, Mehmet
Jarrahpour, Aliasghar
Ebrahimi, Edris
Büyükgüngör, Orhan
author_sort Yalçın, Şerife Pınar
collection PubMed
description The stabilized conformation of the title compound, C(36)H(25)NO(3), 4-(9-anthryl)-1-(2-methoxyphenyl)-spiro[azetid­in-3,9′-xanthen]-2-one, may be compared with that of the isomeric compound 4-(9-anthr­yl)-1-(4-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one. In the title isomer, the meth­oxy group is slightly twisted out of the plane of the attached benzene ring, with a C—O—C—C torsion angle of 31.5 (2)°. Its β-lactam ring is essentially planar, with a maximum deviation of −0.021 (1) Å. The β-lactam ring makes dihedral angles of 18.815 (9), 83.33 (7) and 53.62 (8)° with the mean planes of the benzene, xanthene and anthracene ring systems, respectively. The structure is stabilized by C—H⋯π, C—H⋯N and C—H⋯O inter­actions.
format Text
id pubmed-2968572
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29685722010-12-30 4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one Yalçın, Şerife Pınar Akkurt, Mehmet Jarrahpour, Aliasghar Ebrahimi, Edris Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers The stabilized conformation of the title compound, C(36)H(25)NO(3), 4-(9-anthryl)-1-(2-methoxyphenyl)-spiro[azetid­in-3,9′-xanthen]-2-one, may be compared with that of the isomeric compound 4-(9-anthr­yl)-1-(4-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one. In the title isomer, the meth­oxy group is slightly twisted out of the plane of the attached benzene ring, with a C—O—C—C torsion angle of 31.5 (2)°. Its β-lactam ring is essentially planar, with a maximum deviation of −0.021 (1) Å. The β-lactam ring makes dihedral angles of 18.815 (9), 83.33 (7) and 53.62 (8)° with the mean planes of the benzene, xanthene and anthracene ring systems, respectively. The structure is stabilized by C—H⋯π, C—H⋯N and C—H⋯O inter­actions. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968572/ /pubmed/21582278 http://dx.doi.org/10.1107/S1600536809005200 Text en © Yalçın et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yalçın, Şerife Pınar
Akkurt, Mehmet
Jarrahpour, Aliasghar
Ebrahimi, Edris
Büyükgüngör, Orhan
4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one
title 4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one
title_full 4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one
title_fullStr 4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one
title_full_unstemmed 4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one
title_short 4-(9-Anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one
title_sort 4-(9-anthr­yl)-1-(2-methoxy­phen­yl)spiro­[azetidin-3,9′-xanthen]-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968572/
https://www.ncbi.nlm.nih.gov/pubmed/21582278
http://dx.doi.org/10.1107/S1600536809005200
work_keys_str_mv AT yalcınserifepınar 49anthryl12methoxyphenylspiroazetidin39xanthen2one
AT akkurtmehmet 49anthryl12methoxyphenylspiroazetidin39xanthen2one
AT jarrahpouraliasghar 49anthryl12methoxyphenylspiroazetidin39xanthen2one
AT ebrahimiedris 49anthryl12methoxyphenylspiroazetidin39xanthen2one
AT buyukgungororhan 49anthryl12methoxyphenylspiroazetidin39xanthen2one

Ejemplares similares