1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone

In the title compound, C(14)H(14)BrNO(2)S, there are two similar non-equivalent mol­ecules in the asymmetric unit, displaying three chiral centres each. In the crystal structure, they are linked by inter­molecular N—H⋯O hydrogen bonds to form infinite chains, which are in turn connected by weak Br⋯H...

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Detalles Bibliográficos
Autores principales: Palamarchuk, G. V., Borisov, O. V., Kovalenko, S. S., Chernykh, V. P., Kovalenko, S. M., Baumer, V. N., Shishkin, O. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968576/
https://www.ncbi.nlm.nih.gov/pubmed/21582133
http://dx.doi.org/10.1107/S160053680900347X
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author Palamarchuk, G. V.
Borisov, O. V.
Kovalenko, S. S.
Chernykh, V. P.
Kovalenko, S. M.
Baumer, V. N.
Shishkin, O. V.
author_facet Palamarchuk, G. V.
Borisov, O. V.
Kovalenko, S. S.
Chernykh, V. P.
Kovalenko, S. M.
Baumer, V. N.
Shishkin, O. V.
author_sort Palamarchuk, G. V.
collection PubMed
description In the title compound, C(14)H(14)BrNO(2)S, there are two similar non-equivalent mol­ecules in the asymmetric unit, displaying three chiral centres each. In the crystal structure, they are linked by inter­molecular N—H⋯O hydrogen bonds to form infinite chains, which are in turn connected by weak Br⋯H and S⋯H inter­actions.
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spelling pubmed-29685762010-12-30 1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone Palamarchuk, G. V. Borisov, O. V. Kovalenko, S. S. Chernykh, V. P. Kovalenko, S. M. Baumer, V. N. Shishkin, O. V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(14)BrNO(2)S, there are two similar non-equivalent mol­ecules in the asymmetric unit, displaying three chiral centres each. In the crystal structure, they are linked by inter­molecular N—H⋯O hydrogen bonds to form infinite chains, which are in turn connected by weak Br⋯H and S⋯H inter­actions. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968576/ /pubmed/21582133 http://dx.doi.org/10.1107/S160053680900347X Text en © Palamarchuk et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Palamarchuk, G. V.
Borisov, O. V.
Kovalenko, S. S.
Chernykh, V. P.
Kovalenko, S. M.
Baumer, V. N.
Shishkin, O. V.
1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone
title 1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone
title_full 1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone
title_fullStr 1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone
title_full_unstemmed 1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone
title_short 1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone
title_sort 1-(8-bromo-2-methyl-4-thioxo-3,4,5,6-tetra­hydro-2h-2,6-methano-1,3-benzoxazocin-11-yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968576/
https://www.ncbi.nlm.nih.gov/pubmed/21582133
http://dx.doi.org/10.1107/S160053680900347X
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