2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose

X-ray crystallography unequivocally confirmed the stereochemistry of the C atom at position 2 in the carbon scaffold of the title mol­ecule, C(10)H(18)O(4). The pyran­ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration. The abs...

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Detalles Bibliográficos
Autores principales: Booth, K. Victoria, Jenkinson, Sarah F., Fleet, George W. J., Watkin, David J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968580/
https://www.ncbi.nlm.nih.gov/pubmed/21582225
http://dx.doi.org/10.1107/S1600536809005777
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author Booth, K. Victoria
Jenkinson, Sarah F.
Fleet, George W. J.
Watkin, David J.
author_facet Booth, K. Victoria
Jenkinson, Sarah F.
Fleet, George W. J.
Watkin, David J.
author_sort Booth, K. Victoria
collection PubMed
description X-ray crystallography unequivocally confirmed the stereochemistry of the C atom at position 2 in the carbon scaffold of the title mol­ecule, C(10)H(18)O(4). The pyran­ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration. The absolute stereochemistry was determined from the starting material. The crystal structure consists of O—H⋯O hydrogen-bonded chains of mol­ecules running parallel to the b axis.
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spelling pubmed-29685802010-12-30 2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose Booth, K. Victoria Jenkinson, Sarah F. Fleet, George W. J. Watkin, David J. Acta Crystallogr Sect E Struct Rep Online Organic Papers X-ray crystallography unequivocally confirmed the stereochemistry of the C atom at position 2 in the carbon scaffold of the title mol­ecule, C(10)H(18)O(4). The pyran­ose ring exists in a chair conformation with the methyl group on the C atom in the 2 position in an equatorial configuration. The absolute stereochemistry was determined from the starting material. The crystal structure consists of O—H⋯O hydrogen-bonded chains of mol­ecules running parallel to the b axis. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968580/ /pubmed/21582225 http://dx.doi.org/10.1107/S1600536809005777 Text en © Booth et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Booth, K. Victoria
Jenkinson, Sarah F.
Fleet, George W. J.
Watkin, David J.
2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose
title 2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose
title_full 2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose
title_fullStr 2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose
title_full_unstemmed 2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose
title_short 2-De­oxy-2,3-O-isopropyl­idene-2,4-di-C-methyl-β-l-arabinose
title_sort 2-de­oxy-2,3-o-isopropyl­idene-2,4-di-c-methyl-β-l-arabinose
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968580/
https://www.ncbi.nlm.nih.gov/pubmed/21582225
http://dx.doi.org/10.1107/S1600536809005777
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AT fleetgeorgewj 2deoxy23oisopropylidene24dicmethylblarabinose
AT watkindavidj 2deoxy23oisopropylidene24dicmethylblarabinose

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