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Poly[[[μ-1,1′-(butane-1,4-diyl)diimidazole-κ(2) N (3):N (3′)](μ-cyclohexane-1,4-dicarboxylato-κ(4) O (1),O (1′):O (4),O (4′))nickel(II)] 0.25-hydrate]
In the title coordination polymer, {[Ni(C(8)H(10)O(4))(C(10)H(14)N(4))]·0.25H(2)O}(n), the coordination of the Ni(II) ion is distorted octahedral. The 1,1′-(butane-1,4-diyl)diimidazole ligand and the cyclohexane-1,4-dicarboxylate dianion bridge metal centres, forming a two-dimensional (4,4) netw...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968582/ https://www.ncbi.nlm.nih.gov/pubmed/21582053 http://dx.doi.org/10.1107/S1600536809004024 |
Sumario: | In the title coordination polymer, {[Ni(C(8)H(10)O(4))(C(10)H(14)N(4))]·0.25H(2)O}(n), the coordination of the Ni(II) ion is distorted octahedral. The 1,1′-(butane-1,4-diyl)diimidazole ligand and the cyclohexane-1,4-dicarboxylate dianion bridge metal centres, forming a two-dimensional (4,4) network. The network is consolidated by O—H⋯O hydrogen bonds between the statistically occupied water molecules and O atoms of the two carboxylate groups. |
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