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Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate
The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octahedrally coordinated Ru center with the arene occupying three sites. Two Ru—Cl bonds and one Ru–carbene bond complete the distorted octahedron. The carbene portion of the ligand is a benzimidazole ring...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968587/ https://www.ncbi.nlm.nih.gov/pubmed/21582038 http://dx.doi.org/10.1107/S160053680900350X |
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author | Arslan, Hakan VanDerveer, Don Yaşar, Sedat Özdemir, İsmail Çetinkaya, Bekir |
author_facet | Arslan, Hakan VanDerveer, Don Yaşar, Sedat Özdemir, İsmail Çetinkaya, Bekir |
author_sort | Arslan, Hakan |
collection | PubMed |
description | The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octahedrally coordinated Ru center with the arene occupying three sites. Two Ru—Cl bonds and one Ru–carbene bond complete the distorted octahedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C(6)H(2)(CH(3))(3) arene group by a CH(2) bridge. This leads to a system with very little apparent strain. A dichloromethane solvent molecule completes the crystal structure. Further stabilization is accomplished via C—H⋯N and C—H⋯Cl interactions. |
format | Text |
id | pubmed-2968587 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29685872010-12-30 Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate Arslan, Hakan VanDerveer, Don Yaşar, Sedat Özdemir, İsmail Çetinkaya, Bekir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octahedrally coordinated Ru center with the arene occupying three sites. Two Ru—Cl bonds and one Ru–carbene bond complete the distorted octahedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C(6)H(2)(CH(3))(3) arene group by a CH(2) bridge. This leads to a system with very little apparent strain. A dichloromethane solvent molecule completes the crystal structure. Further stabilization is accomplished via C—H⋯N and C—H⋯Cl interactions. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968587/ /pubmed/21582038 http://dx.doi.org/10.1107/S160053680900350X Text en © Arslan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Arslan, Hakan VanDerveer, Don Yaşar, Sedat Özdemir, İsmail Çetinkaya, Bekir Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate |
title | Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate |
title_full | Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate |
title_fullStr | Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate |
title_full_unstemmed | Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate |
title_short | Dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate |
title_sort | dichlorido[1-(2-methylbenzyl)-3-(η(6)-2,4,6-trimethylbenzyl)-1h-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(ii) dichloromethane solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968587/ https://www.ncbi.nlm.nih.gov/pubmed/21582038 http://dx.doi.org/10.1107/S160053680900350X |
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