Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate

The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octa­hedrally coordinated Ru center with the arene occupying three sites. Two Ru—Cl bonds and one Ru–carbene bond complete the distorted octa­hedron. The carbene portion of the ligand is a benzimidazole ring...

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Autores principales: Arslan, Hakan, VanDerveer, Don, Yaşar, Sedat, Özdemir, İsmail, Çetinkaya, Bekir
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968587/
https://www.ncbi.nlm.nih.gov/pubmed/21582038
http://dx.doi.org/10.1107/S160053680900350X
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author Arslan, Hakan
VanDerveer, Don
Yaşar, Sedat
Özdemir, İsmail
Çetinkaya, Bekir
author_facet Arslan, Hakan
VanDerveer, Don
Yaşar, Sedat
Özdemir, İsmail
Çetinkaya, Bekir
author_sort Arslan, Hakan
collection PubMed
description The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octa­hedrally coordinated Ru center with the arene occupying three sites. Two Ru—Cl bonds and one Ru–carbene bond complete the distorted octa­hedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C(6)H(2)(CH(3))(3) arene group by a CH(2) bridge. This leads to a system with very little apparent strain. A dichloro­methane solvent mol­ecule completes the crystal structure. Further stabilization is accomplished via C—H⋯N and C—H⋯Cl interactions.
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spelling pubmed-29685872010-12-30 Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate Arslan, Hakan VanDerveer, Don Yaşar, Sedat Özdemir, İsmail Çetinkaya, Bekir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octa­hedrally coordinated Ru center with the arene occupying three sites. Two Ru—Cl bonds and one Ru–carbene bond complete the distorted octa­hedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C(6)H(2)(CH(3))(3) arene group by a CH(2) bridge. This leads to a system with very little apparent strain. A dichloro­methane solvent mol­ecule completes the crystal structure. Further stabilization is accomplished via C—H⋯N and C—H⋯Cl interactions. International Union of Crystallography 2009-02-04 /pmc/articles/PMC2968587/ /pubmed/21582038 http://dx.doi.org/10.1107/S160053680900350X Text en © Arslan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Arslan, Hakan
VanDerveer, Don
Yaşar, Sedat
Özdemir, İsmail
Çetinkaya, Bekir
Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate
title Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate
title_full Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate
title_fullStr Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate
title_full_unstemmed Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate
title_short Dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1H-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(II) dichloro­methane solvate
title_sort dichlorido[1-(2-methyl­benz­yl)-3-(η(6)-2,4,6-trimethyl­benz­yl)-1h-2,3-dihydro­benzimidazol-2-yl­idene]ruthenium(ii) dichloro­methane solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968587/
https://www.ncbi.nlm.nih.gov/pubmed/21582038
http://dx.doi.org/10.1107/S160053680900350X
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AT vanderveerdon dichlorido12methylbenzyl3ē6246trimethylbenzyl1h23dihydrobenzimidazol2ylidenerutheniumiidichloromethanesolvate
AT yasarsedat dichlorido12methylbenzyl3ē6246trimethylbenzyl1h23dihydrobenzimidazol2ylidenerutheniumiidichloromethanesolvate
AT ozdemirismail dichlorido12methylbenzyl3ē6246trimethylbenzyl1h23dihydrobenzimidazol2ylidenerutheniumiidichloromethanesolvate
AT cetinkayabekir dichlorido12methylbenzyl3ē6246trimethylbenzyl1h23dihydrobenzimidazol2ylidenerutheniumiidichloromethanesolvate

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