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Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]

In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol (L) ligands, and by two N atoms from two axial thio...

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Detalles Bibliográficos
Autor principal: Chu, Zhao-lian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968591/
https://www.ncbi.nlm.nih.gov/pubmed/21582072
http://dx.doi.org/10.1107/S1600536809005121
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author Chu, Zhao-lian
author_facet Chu, Zhao-lian
author_sort Chu, Zhao-lian
collection PubMed
description In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol (L) ligands, and by two N atoms from two axial thio­cyanate anions [Co—N = 2.104 (3)–2.144 (3) Å]. The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane. The dimethyl­formamide and solvent water mol­ecules participate in inter­molecular O—H⋯O and O—H⋯S hydrogen bonds, which consolidate the crystal packing.
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spelling pubmed-29685912010-12-30 Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate] Chu, Zhao-lian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol (L) ligands, and by two N atoms from two axial thio­cyanate anions [Co—N = 2.104 (3)–2.144 (3) Å]. The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane. The dimethyl­formamide and solvent water mol­ecules participate in inter­molecular O—H⋯O and O—H⋯S hydrogen bonds, which consolidate the crystal packing. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968591/ /pubmed/21582072 http://dx.doi.org/10.1107/S1600536809005121 Text en © Zhao-lian Chu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chu, Zhao-lian
Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]
title Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]
title_full Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]
title_fullStr Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]
title_full_unstemmed Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]
title_short Poly[[[diisothio­cyanato­cobalt(II)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]
title_sort poly[[[diisothio­cyanato­cobalt(ii)]-bis­[μ-4-tert-butyl-2,6-bis­(1,2,4-triazol-1-ylmeth­yl)phenol]] dimethyl­formamide disolvate dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968591/
https://www.ncbi.nlm.nih.gov/pubmed/21582072
http://dx.doi.org/10.1107/S1600536809005121
work_keys_str_mv AT chuzhaolian polydiisothiocyanatocobaltiibism4tertbutyl26bis124triazol1ylmethylphenoldimethylformamidedisolvatedihydrate