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Tetraaquabis(nicotinamide-κN (1))cobalt(II) bis(2-fluorobenzoate)
The title complex, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(4)FO(2))(2), contains one Co(II) atom (site symmetry [Image: see text]), two monodentate nicotinamide (NA) ligands, four coordinated water molecules and two 2-fluorobenzoate (FB) anions. The four O atoms in the equatorial plane around the...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968619/ https://www.ncbi.nlm.nih.gov/pubmed/21582108 http://dx.doi.org/10.1107/S1600536809006771 |
Sumario: | The title complex, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(4)FO(2))(2), contains one Co(II) atom (site symmetry [Image: see text]), two monodentate nicotinamide (NA) ligands, four coordinated water molecules and two 2-fluorobenzoate (FB) anions. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.8 (3)°, while the pyridine and benzene rings are oriented at a dihedral angle of 7.97 (12)°. In the crystal structure, molecules are linked by O—H⋯O, N—H⋯O and N—H⋯F hydrogen bonds, forming an infinite three-dimensional network. π–π Contacts between the pyridine and benzene rings [centroid–centroid distance = 3.673 (3) Å] may further stabilize the crystal structure. |
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