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Tetra­aqua­bis(nicotinamide-κN (1))cobalt(II) bis­(2-fluoro­benzoate)

The title complex, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(4)FO(2))(2), contains one Co(II) atom (site symmetry [Image: see text]), two monodentate nicotin­amide (NA) ligands, four coordinated water mol­ecules and two 2-fluoro­benzoate (FB) anions. The four O atoms in the equatorial plane around the...

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Detalles Bibliográficos
Autores principales: Özbek, F. Elif, Tercan, Barış, Şahin, Ertan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968619/
https://www.ncbi.nlm.nih.gov/pubmed/21582108
http://dx.doi.org/10.1107/S1600536809006771
Descripción
Sumario:The title complex, [Co(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(7)H(4)FO(2))(2), contains one Co(II) atom (site symmetry [Image: see text]), two monodentate nicotin­amide (NA) ligands, four coordinated water mol­ecules and two 2-fluoro­benzoate (FB) anions. The four O atoms in the equatorial plane around the Co atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 29.8 (3)°, while the pyridine and benzene rings are oriented at a dihedral angle of 7.97 (12)°. In the crystal structure, mol­ecules are linked by O—H⋯O, N—H⋯O and N—H⋯F hydrogen bonds, forming an infinite three-dimensional network. π–π Contacts between the pyridine and benzene rings [centroid–centroid distance = 3.673 (3) Å] may further stabilize the crystal structure.