Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)]

In the centrosymmetric dimeric title compound, [Cu(2)(C(3)H(6)NS(2))(4)], the Cu(II) atom is five-coordinate in a square-pyramidal environment. The basal coordination positions are occupied by four S atoms from two dimethyl­dithio­carbamate ligands and the apical coordination position is occupied by...

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Detalles Bibliográficos
Autores principales: Fan, Le-Qing, Wu, Ji-Huai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968622/
https://www.ncbi.nlm.nih.gov/pubmed/21582093
http://dx.doi.org/10.1107/S1600536809006230
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author Fan, Le-Qing
Wu, Ji-Huai
author_facet Fan, Le-Qing
Wu, Ji-Huai
author_sort Fan, Le-Qing
collection PubMed
description In the centrosymmetric dimeric title compound, [Cu(2)(C(3)H(6)NS(2))(4)], the Cu(II) atom is five-coordinate in a square-pyramidal environment. The basal coordination positions are occupied by four S atoms from two dimethyl­dithio­carbamate ligands and the apical coordination position is occupied by an S atom also bonded to the other Cu atom.
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spelling pubmed-29686222010-12-30 Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)] Fan, Le-Qing Wu, Ji-Huai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dimeric title compound, [Cu(2)(C(3)H(6)NS(2))(4)], the Cu(II) atom is five-coordinate in a square-pyramidal environment. The basal coordination positions are occupied by four S atoms from two dimethyl­dithio­carbamate ligands and the apical coordination position is occupied by an S atom also bonded to the other Cu atom. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968622/ /pubmed/21582093 http://dx.doi.org/10.1107/S1600536809006230 Text en © Fan and Wu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fan, Le-Qing
Wu, Ji-Huai
Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)]
title Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)]
title_full Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)]
title_fullStr Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)]
title_full_unstemmed Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)]
title_short Bis(μ-N,N-dimethyl­dithio­carbamato-κ(3) S,S′:S)bis­[(N,N-dimethyl­dithio­carbamato-κ(2) S,S′)copper(II)]
title_sort bis(μ-n,n-dimethyl­dithio­carbamato-κ(3) s,s′:s)bis­[(n,n-dimethyl­dithio­carbamato-κ(2) s,s′)copper(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968622/
https://www.ncbi.nlm.nih.gov/pubmed/21582093
http://dx.doi.org/10.1107/S1600536809006230
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