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5-Bromo-17-nitro-26,28-prop-2-en­oxy-25,27-dipropoxycalix[4]arene

Mol­ecules of the title compound, C(40)H(42)BrNO(6), are located on a crystallographic twofold rotation axis. As a result, the nitro group and bromine residue are mutually disordered with equal occupancies. The prop­oxy-substituted aromatic rings are close to parallel to each other [dihedral angle =...

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Detalles Bibliográficos
Autores principales: Hippius, Catharina, Würthner, Frank, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968623/
https://www.ncbi.nlm.nih.gov/pubmed/21582269
http://dx.doi.org/10.1107/S160053680900659X
Descripción
Sumario:Mol­ecules of the title compound, C(40)H(42)BrNO(6), are located on a crystallographic twofold rotation axis. As a result, the nitro group and bromine residue are mutually disordered with equal occupancies. The prop­oxy-substituted aromatic rings are close to parallel to each other [dihedral angle = 21.24 (1)°], whereas the propen­oxy-substituted rings enclose a dihedral angle of 70.44 (1)°. The dihedral angles between the methyl­ene C atoms and the aromatic rings shows that the propen­oxy substituted rings are bent away from the calixarene cavity [dihedral angle between the planes = 35.22 (8)°], whereas the prop­oxy-substituted rings are almost perpendicular [79.38 (10)°] to the plane of the methyl­ene C atoms.