Guanidinium tetra­bromidomercurate(II)

The Hg atoms in the crystal structure of the title compound, (CH(6)N(3))(2)[HgBr(4)], are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) tetra­hedral ions are linked to the [C(NH(2))(3)](+) ions by bromine–hydrogen bonds, forming a three-dimensional network. In the struc...

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Autores principales: Terao, Hiromitsu, Gesing, Thorsten M., Ishihara, Hideta, Furukawa, Yoshihiro, Gowda, B. Thimme
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968626/
https://www.ncbi.nlm.nih.gov/pubmed/21582096
http://dx.doi.org/10.1107/S1600536809005972
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author Terao, Hiromitsu
Gesing, Thorsten M.
Ishihara, Hideta
Furukawa, Yoshihiro
Gowda, B. Thimme
author_facet Terao, Hiromitsu
Gesing, Thorsten M.
Ishihara, Hideta
Furukawa, Yoshihiro
Gowda, B. Thimme
author_sort Terao, Hiromitsu
collection PubMed
description The Hg atoms in the crystal structure of the title compound, (CH(6)N(3))(2)[HgBr(4)], are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) tetra­hedral ions are linked to the [C(NH(2))(3)](+) ions by bromine–hydrogen bonds, forming a three-dimensional network. In the structure, the anions are located on special positions. The two different Hg⋯Br distances of 2.664 (1) and 2.559 (1) Å observed in the tetra­bromidomercurate unit are due to the connection of Br atoms to different number of H atoms.
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spelling pubmed-29686262010-12-30 Guanidinium tetra­bromidomercurate(II) Terao, Hiromitsu Gesing, Thorsten M. Ishihara, Hideta Furukawa, Yoshihiro Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Hg atoms in the crystal structure of the title compound, (CH(6)N(3))(2)[HgBr(4)], are tetra­hedrally coordinated by four Br atoms and the resulting [HgBr(4)](2−) tetra­hedral ions are linked to the [C(NH(2))(3)](+) ions by bromine–hydrogen bonds, forming a three-dimensional network. In the structure, the anions are located on special positions. The two different Hg⋯Br distances of 2.664 (1) and 2.559 (1) Å observed in the tetra­bromidomercurate unit are due to the connection of Br atoms to different number of H atoms. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968626/ /pubmed/21582096 http://dx.doi.org/10.1107/S1600536809005972 Text en © Terao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Terao, Hiromitsu
Gesing, Thorsten M.
Ishihara, Hideta
Furukawa, Yoshihiro
Gowda, B. Thimme
Guanidinium tetra­bromidomercurate(II)
title Guanidinium tetra­bromidomercurate(II)
title_full Guanidinium tetra­bromidomercurate(II)
title_fullStr Guanidinium tetra­bromidomercurate(II)
title_full_unstemmed Guanidinium tetra­bromidomercurate(II)
title_short Guanidinium tetra­bromidomercurate(II)
title_sort guanidinium tetra­bromidomercurate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968626/
https://www.ncbi.nlm.nih.gov/pubmed/21582096
http://dx.doi.org/10.1107/S1600536809005972
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AT gesingthorstenm guanidiniumtetrabromidomercurateii
AT ishiharahideta guanidiniumtetrabromidomercurateii
AT furukawayoshihiro guanidiniumtetrabromidomercurateii
AT gowdabthimme guanidiniumtetrabromidomercurateii

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