Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]

The mol­ecule of the title compound, [Pb(2)(C(9)H(5)ClNO)(2)(C(2)H(3)O(2))(2)], lies about a center of inversion. The Pb(II) atom is chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center....

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Detalles Bibliográficos
Autores principales: Mohammadnezhad Sh., Gholamhossein, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968633/
https://www.ncbi.nlm.nih.gov/pubmed/21582051
http://dx.doi.org/10.1107/S1600536809003559
Descripción
Sumario:The mol­ecule of the title compound, [Pb(2)(C(9)H(5)ClNO)(2)(C(2)H(3)O(2))(2)], lies about a center of inversion. The Pb(II) atom is chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center. The geometry approximates a distorted Ψ-fac octa­hedron in which one of the sites is occupied by a stereochemically active lone pair.

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