Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]

The mol­ecule of the title compound, [Pb(2)(C(9)H(5)ClNO)(2)(C(2)H(3)O(2))(2)], lies about a center of inversion. The Pb(II) atom is chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center....

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Detalles Bibliográficos
Autores principales: Mohammadnezhad Sh., Gholamhossein, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968633/
https://www.ncbi.nlm.nih.gov/pubmed/21582051
http://dx.doi.org/10.1107/S1600536809003559
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author Mohammadnezhad Sh., Gholamhossein
Amini, Mostafa M.
Ng, Seik Weng
author_facet Mohammadnezhad Sh., Gholamhossein
Amini, Mostafa M.
Ng, Seik Weng
author_sort Mohammadnezhad Sh., Gholamhossein
collection PubMed
description The mol­ecule of the title compound, [Pb(2)(C(9)H(5)ClNO)(2)(C(2)H(3)O(2))(2)], lies about a center of inversion. The Pb(II) atom is chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center. The geometry approximates a distorted Ψ-fac octa­hedron in which one of the sites is occupied by a stereochemically active lone pair.
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spelling pubmed-29686332010-12-30 Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)] Mohammadnezhad Sh., Gholamhossein Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [Pb(2)(C(9)H(5)ClNO)(2)(C(2)H(3)O(2))(2)], lies about a center of inversion. The Pb(II) atom is chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center. The geometry approximates a distorted Ψ-fac octa­hedron in which one of the sites is occupied by a stereochemically active lone pair. International Union of Crystallography 2009-02-11 /pmc/articles/PMC2968633/ /pubmed/21582051 http://dx.doi.org/10.1107/S1600536809003559 Text en © Mohammadnezhad Sh. et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mohammadnezhad Sh., Gholamhossein
Amini, Mostafa M.
Ng, Seik Weng
Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]
title Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]
title_full Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]
title_fullStr Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]
title_full_unstemmed Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]
title_short Bis(μ-5-chloro­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(acetato-κ(2) O,O′)lead(II)]
title_sort bis(μ-5-chloro­quinolin-8-olato)-κ(3) n,o:o;κ(3) o:n,o-bis­[(acetato-κ(2) o,o′)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968633/
https://www.ncbi.nlm.nih.gov/pubmed/21582051
http://dx.doi.org/10.1107/S1600536809003559
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