Bis(μ-2-methyl­quinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis­[(methanol-κO)(nitrato-κ(2) O,O′)lead(II)]

The mol­ecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. Wh...

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Detalles Bibliográficos
Autores principales: Mohammadnezhad Sh., Gholamhossein, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968636/
https://www.ncbi.nlm.nih.gov/pubmed/21582049
http://dx.doi.org/10.1107/S1600536809003547
Descripción
Sumario:The mol­ecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. When a longer Pb⋯O inter­action is considered, the geometry approximates a Ψ-cube in which one of the sites is occupied by a stereochemically active lone pair.

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