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Bis(μ-2-methylquinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis[(methanol-κO)(nitrato-κ(2) O,O′)lead(II)]
The molecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. Wh...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968636/ https://www.ncbi.nlm.nih.gov/pubmed/21582049 http://dx.doi.org/10.1107/S1600536809003547 |
Sumario: | The molecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. When a longer Pb⋯O interaction is considered, the geometry approximates a Ψ-cube in which one of the sites is occupied by a stereochemically active lone pair. |
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