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Bis(μ-2-methylquinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis[(methanol-κO)(nitrato-κ(2) O,O′)lead(II)]
The molecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. Wh...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968636/ https://www.ncbi.nlm.nih.gov/pubmed/21582049 http://dx.doi.org/10.1107/S1600536809003547 |
| _version_ | 1782189939281100800 |
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| author | Mohammadnezhad Sh., Gholamhossein Amini, Mostafa M. Ng, Seik Weng |
| author_facet | Mohammadnezhad Sh., Gholamhossein Amini, Mostafa M. Ng, Seik Weng |
| author_sort | Mohammadnezhad Sh., Gholamhossein |
| collection | PubMed |
| description | The molecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. When a longer Pb⋯O interaction is considered, the geometry approximates a Ψ-cube in which one of the sites is occupied by a stereochemically active lone pair. |
| format | Text |
| id | pubmed-2968636 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29686362010-12-30 Bis(μ-2-methylquinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis[(methanol-κO)(nitrato-κ(2) O,O′)lead(II)] Mohammadnezhad Sh., Gholamhossein Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The molecule of the title compound, [Pb(2)(C(10)H(8)NO)(2)(NO(3))(2)(CH(3)OH)(2)], lies about a centre of inversion. The Pb atom is chelated by nitrate and substituted quinolin-8-olate anions. The O atom of the quinolin-8-olate also bridges, to confer a six-coordinate status on the metal centre. When a longer Pb⋯O interaction is considered, the geometry approximates a Ψ-cube in which one of the sites is occupied by a stereochemically active lone pair. International Union of Crystallography 2009-02-11 /pmc/articles/PMC2968636/ /pubmed/21582049 http://dx.doi.org/10.1107/S1600536809003547 Text en © Mohammadnezhad Sh. et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Mohammadnezhad Sh., Gholamhossein Amini, Mostafa M. Ng, Seik Weng Bis(μ-2-methylquinolin-8-olato)-κ(3) N,O:O;κ(3) O:N,O-bis[(methanol-κO)(nitrato-κ(2) O,O′)lead(II)] |
| title | Bis(μ-2-methylquinolin-8-olato)-κ(3)
N,O:O;κ(3)
O:N,O-bis[(methanol-κO)(nitrato-κ(2)
O,O′)lead(II)] |
| title_full | Bis(μ-2-methylquinolin-8-olato)-κ(3)
N,O:O;κ(3)
O:N,O-bis[(methanol-κO)(nitrato-κ(2)
O,O′)lead(II)] |
| title_fullStr | Bis(μ-2-methylquinolin-8-olato)-κ(3)
N,O:O;κ(3)
O:N,O-bis[(methanol-κO)(nitrato-κ(2)
O,O′)lead(II)] |
| title_full_unstemmed | Bis(μ-2-methylquinolin-8-olato)-κ(3)
N,O:O;κ(3)
O:N,O-bis[(methanol-κO)(nitrato-κ(2)
O,O′)lead(II)] |
| title_short | Bis(μ-2-methylquinolin-8-olato)-κ(3)
N,O:O;κ(3)
O:N,O-bis[(methanol-κO)(nitrato-κ(2)
O,O′)lead(II)] |
| title_sort | bis(μ-2-methylquinolin-8-olato)-κ(3)
n,o:o;κ(3)
o:n,o-bis[(methanol-κo)(nitrato-κ(2)
o,o′)lead(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968636/ https://www.ncbi.nlm.nih.gov/pubmed/21582049 http://dx.doi.org/10.1107/S1600536809003547 |
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