1,3-Benzothia­zolium tetra­chlorido­aurate(III) tetra­hydro­furan solvate

In the crystal structure of the title ionic compound (C(7)H(6)NS)[AuCl(4)]·C(4)H(8)O, the [AuCl(4)](−) anion shows a typical square-planar geometry. Numerous weak C—H⋯Cl hydrogen bonds between [AuCl(4)](−) and the 1,3-benzothia­zolium units form layers comprised of 24-membered rings in which hydroge...

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Detalles Bibliográficos
Autores principales: Hagos, Tesfamariam K., Nogai, Stefan D., Dobrzańska, Liliana, Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968643/
https://www.ncbi.nlm.nih.gov/pubmed/21582047
http://dx.doi.org/10.1107/S1600536809003572
Descripción
Sumario:In the crystal structure of the title ionic compound (C(7)H(6)NS)[AuCl(4)]·C(4)H(8)O, the [AuCl(4)](−) anion shows a typical square-planar geometry. Numerous weak C—H⋯Cl hydrogen bonds between [AuCl(4)](−) and the 1,3-benzothia­zolium units form layers comprised of 24-membered rings in which hydrogen-bonded tetra­hydro­furan (THF) solvent mol­ecules are accommodated. C—H⋯Cl inter­actions between THF and [AuCl(4)](−) from adjacent layers result in bilayers. These are further stabilized by π–π inter­actions between the thia­zole and benzene rings [centroid–centroid distance = 3.971 (3) Å], resulting in the formation of a three-dimensional supra­molecular assembly.

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