Cargando…
1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate
In the crystal structure of the title ionic compound (C(7)H(6)NS)[AuCl(4)]·C(4)H(8)O, the [AuCl(4)](−) anion shows a typical square-planar geometry. Numerous weak C—H⋯Cl hydrogen bonds between [AuCl(4)](−) and the 1,3-benzothiazolium units form layers comprised of 24-membered rings in which hydroge...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968643/ https://www.ncbi.nlm.nih.gov/pubmed/21582047 http://dx.doi.org/10.1107/S1600536809003572 |
| _version_ | 1782189941170634752 |
|---|---|
| author | Hagos, Tesfamariam K. Nogai, Stefan D. Dobrzańska, Liliana Cronje, Stephanie Raubenheimer, Helgard G. |
| author_facet | Hagos, Tesfamariam K. Nogai, Stefan D. Dobrzańska, Liliana Cronje, Stephanie Raubenheimer, Helgard G. |
| author_sort | Hagos, Tesfamariam K. |
| collection | PubMed |
| description | In the crystal structure of the title ionic compound (C(7)H(6)NS)[AuCl(4)]·C(4)H(8)O, the [AuCl(4)](−) anion shows a typical square-planar geometry. Numerous weak C—H⋯Cl hydrogen bonds between [AuCl(4)](−) and the 1,3-benzothiazolium units form layers comprised of 24-membered rings in which hydrogen-bonded tetrahydrofuran (THF) solvent molecules are accommodated. C—H⋯Cl interactions between THF and [AuCl(4)](−) from adjacent layers result in bilayers. These are further stabilized by π–π interactions between the thiazole and benzene rings [centroid–centroid distance = 3.971 (3) Å], resulting in the formation of a three-dimensional supramolecular assembly. |
| format | Text |
| id | pubmed-2968643 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29686432010-12-30 1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate Hagos, Tesfamariam K. Nogai, Stefan D. Dobrzańska, Liliana Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title ionic compound (C(7)H(6)NS)[AuCl(4)]·C(4)H(8)O, the [AuCl(4)](−) anion shows a typical square-planar geometry. Numerous weak C—H⋯Cl hydrogen bonds between [AuCl(4)](−) and the 1,3-benzothiazolium units form layers comprised of 24-membered rings in which hydrogen-bonded tetrahydrofuran (THF) solvent molecules are accommodated. C—H⋯Cl interactions between THF and [AuCl(4)](−) from adjacent layers result in bilayers. These are further stabilized by π–π interactions between the thiazole and benzene rings [centroid–centroid distance = 3.971 (3) Å], resulting in the formation of a three-dimensional supramolecular assembly. International Union of Crystallography 2009-02-06 /pmc/articles/PMC2968643/ /pubmed/21582047 http://dx.doi.org/10.1107/S1600536809003572 Text en © Hagos et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Hagos, Tesfamariam K. Nogai, Stefan D. Dobrzańska, Liliana Cronje, Stephanie Raubenheimer, Helgard G. 1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate |
| title | 1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate |
| title_full | 1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate |
| title_fullStr | 1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate |
| title_full_unstemmed | 1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate |
| title_short | 1,3-Benzothiazolium tetrachloridoaurate(III) tetrahydrofuran solvate |
| title_sort | 1,3-benzothiazolium tetrachloridoaurate(iii) tetrahydrofuran solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968643/ https://www.ncbi.nlm.nih.gov/pubmed/21582047 http://dx.doi.org/10.1107/S1600536809003572 |
| work_keys_str_mv | AT hagostesfamariamk 13benzothiazoliumtetrachloridoaurateiiitetrahydrofuransolvate AT nogaistefand 13benzothiazoliumtetrachloridoaurateiiitetrahydrofuransolvate AT dobrzanskaliliana 13benzothiazoliumtetrachloridoaurateiiitetrahydrofuransolvate AT cronjestephanie 13benzothiazoliumtetrachloridoaurateiiitetrahydrofuransolvate AT raubenheimerhelgardg 13benzothiazoliumtetrachloridoaurateiiitetrahydrofuransolvate |