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2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide

The title compound, [Fe(2)(C(5)H(5))(2)(C(30)H(22)N(2)O(2))], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methyl­pyridine, forms a twisted mol­ecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbon...

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Detalles Bibliográficos
Autores principales: Gallagher, John F., Alley, Steven, Lough, Alan J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968647/
https://www.ncbi.nlm.nih.gov/pubmed/21582102
http://dx.doi.org/10.1107/S1600536809006278
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author Gallagher, John F.
Alley, Steven
Lough, Alan J.
author_facet Gallagher, John F.
Alley, Steven
Lough, Alan J.
author_sort Gallagher, John F.
collection PubMed
description The title compound, [Fe(2)(C(5)H(5))(2)(C(30)H(22)N(2)O(2))], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methyl­pyridine, forms a twisted mol­ecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intra­molecular C—H⋯π interaction is observed involving a substituted η(5)-C(5)H(4) ring and an ortho H atom of the benzene ring on the opposite side of the mol­ecule. In the crystal structure, there are no classical hydrogen bonds: inter­actions comprise a short C(6)—H⋯π(C(6)) inter­action involving substituted benzene rings and two C—H⋯O=C inter­actions per mol­ecule.
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spelling pubmed-29686472010-12-30 2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide Gallagher, John F. Alley, Steven Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(2)(C(5)H(5))(2)(C(30)H(22)N(2)O(2))], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methyl­pyridine, forms a twisted mol­ecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intra­molecular C—H⋯π interaction is observed involving a substituted η(5)-C(5)H(4) ring and an ortho H atom of the benzene ring on the opposite side of the mol­ecule. In the crystal structure, there are no classical hydrogen bonds: inter­actions comprise a short C(6)—H⋯π(C(6)) inter­action involving substituted benzene rings and two C—H⋯O=C inter­actions per mol­ecule. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968647/ /pubmed/21582102 http://dx.doi.org/10.1107/S1600536809006278 Text en © Gallagher et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gallagher, John F.
Alley, Steven
Lough, Alan J.
2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide
title 2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide
title_full 2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide
title_fullStr 2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide
title_full_unstemmed 2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide
title_short 2-Ferrocenyl-N-(2-ferrocenylbenzo­yl)-N-(4-methyl-2-pyrid­yl)benzamide
title_sort 2-ferrocenyl-n-(2-ferrocenylbenzo­yl)-n-(4-methyl-2-pyrid­yl)benzamide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968647/
https://www.ncbi.nlm.nih.gov/pubmed/21582102
http://dx.doi.org/10.1107/S1600536809006278
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