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2,4-Dimethyl-N-phenyl­benzene­sulfonamide

The asymmetric unit of the crystal structure of the title compound, C(14)H(15)NO(2)S, contains two mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C—SO(2)—NH—C...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Nirmala, P. G., Babitha, K. S., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968648/
https://www.ncbi.nlm.nih.gov/pubmed/21582231
http://dx.doi.org/10.1107/S160053680900573X
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author Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Babitha, K. S.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Babitha, K. S.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The asymmetric unit of the crystal structure of the title compound, C(14)H(15)NO(2)S, contains two mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C—SO(2)—NH—C groups in the two mol­ecules are 46.1 (3) (glide image of mol­ecule 1) and 47.7 (3)° (mol­ecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two mol­ecules. N—H⋯O and C—H⋯O hydrogen bonds pack the mol­ecules into one-dimensional chains in different directions, resulting in a two-dimensional network.
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spelling pubmed-29686482010-12-30 2,4-Dimethyl-N-phenyl­benzene­sulfonamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Babitha, K. S. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the crystal structure of the title compound, C(14)H(15)NO(2)S, contains two mol­ecules. The conformations of the N—C bonds in the C—SO(2)—NH—C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C—SO(2)—NH—C groups in the two mol­ecules are 46.1 (3) (glide image of mol­ecule 1) and 47.7 (3)° (mol­ecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two mol­ecules. N—H⋯O and C—H⋯O hydrogen bonds pack the mol­ecules into one-dimensional chains in different directions, resulting in a two-dimensional network. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968648/ /pubmed/21582231 http://dx.doi.org/10.1107/S160053680900573X Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Nirmala, P. G.
Babitha, K. S.
Fuess, Hartmut
2,4-Dimethyl-N-phenyl­benzene­sulfonamide
title 2,4-Dimethyl-N-phenyl­benzene­sulfonamide
title_full 2,4-Dimethyl-N-phenyl­benzene­sulfonamide
title_fullStr 2,4-Dimethyl-N-phenyl­benzene­sulfonamide
title_full_unstemmed 2,4-Dimethyl-N-phenyl­benzene­sulfonamide
title_short 2,4-Dimethyl-N-phenyl­benzene­sulfonamide
title_sort 2,4-dimethyl-n-phenyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968648/
https://www.ncbi.nlm.nih.gov/pubmed/21582231
http://dx.doi.org/10.1107/S160053680900573X
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