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2,4-Dimethyl-N-phenylbenzenesulfonamide
The asymmetric unit of the crystal structure of the title compound, C(14)H(15)NO(2)S, contains two molecules. The conformations of the N—C bonds in the C—SO(2)—NH—C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C—SO(2)—NH—C...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968648/ https://www.ncbi.nlm.nih.gov/pubmed/21582231 http://dx.doi.org/10.1107/S160053680900573X |
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author | Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Babitha, K. S. Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Babitha, K. S. Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | The asymmetric unit of the crystal structure of the title compound, C(14)H(15)NO(2)S, contains two molecules. The conformations of the N—C bonds in the C—SO(2)—NH—C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C—SO(2)—NH—C groups in the two molecules are 46.1 (3) (glide image of molecule 1) and 47.7 (3)° (molecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two molecules. N—H⋯O and C—H⋯O hydrogen bonds pack the molecules into one-dimensional chains in different directions, resulting in a two-dimensional network. |
format | Text |
id | pubmed-2968648 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29686482010-12-30 2,4-Dimethyl-N-phenylbenzenesulfonamide Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Babitha, K. S. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the crystal structure of the title compound, C(14)H(15)NO(2)S, contains two molecules. The conformations of the N—C bonds in the C—SO(2)—NH—C segments of the structure have trans and gauche torsion angles with the S=O bonds. Furthermore, the torsion angles of the C—SO(2)—NH—C groups in the two molecules are 46.1 (3) (glide image of molecule 1) and 47.7 (3)° (molecule 2). The ortho-methyl groups in the sulfonyl benzene ring are oriented away from the S=O bonds. The two benzene rings are tilted relative to each other by 67.5 (1) and 72.9 (1)° in the two molecules. N—H⋯O and C—H⋯O hydrogen bonds pack the molecules into one-dimensional chains in different directions, resulting in a two-dimensional network. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968648/ /pubmed/21582231 http://dx.doi.org/10.1107/S160053680900573X Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Nirmala, P. G. Babitha, K. S. Fuess, Hartmut 2,4-Dimethyl-N-phenylbenzenesulfonamide |
title | 2,4-Dimethyl-N-phenylbenzenesulfonamide |
title_full | 2,4-Dimethyl-N-phenylbenzenesulfonamide |
title_fullStr | 2,4-Dimethyl-N-phenylbenzenesulfonamide |
title_full_unstemmed | 2,4-Dimethyl-N-phenylbenzenesulfonamide |
title_short | 2,4-Dimethyl-N-phenylbenzenesulfonamide |
title_sort | 2,4-dimethyl-n-phenylbenzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968648/ https://www.ncbi.nlm.nih.gov/pubmed/21582231 http://dx.doi.org/10.1107/S160053680900573X |
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