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3,3-Ethylenedithio-3,3a,4,5,10,10b-hexahydro-2H-furo[2,3-a]carbazole
The title compound, C(16)H(17)NOS(2), consists of a carbazole skeleton with tetrahydrofuran and dithiolane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)°. The cyclohexenone and tetrahydrofuran rings have envelope conf...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968651/ https://www.ncbi.nlm.nih.gov/pubmed/21582250 http://dx.doi.org/10.1107/S1600536809006035 |
Sumario: | The title compound, C(16)H(17)NOS(2), consists of a carbazole skeleton with tetrahydrofuran and dithiolane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)°. The cyclohexenone and tetrahydrofuran rings have envelope conformations, while the dithiolane ring adopts a twist conformation. In the crystal structure, pairs of weak intermolecular N—H⋯S hydrogen bonds link the molecules into centrosymmetric dimers with R (2) (2)(16) ring motifs. Weak C—H⋯π interactions may further stabilize the structure. |
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