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3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole

The title compound, C(16)H(17)NOS(2), consists of a carbazole skeleton with tetra­hydro­furan and dithiol­ane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)°. The cyclo­hexenone and tetra­hydro­furan rings have envelope conf...

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Detalles Bibliográficos
Autores principales: Uludağ, Nesimi, Öztürk, Aslı, Hökelek, Tuncer, Erdoğan, Ümit Işık
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968651/
https://www.ncbi.nlm.nih.gov/pubmed/21582250
http://dx.doi.org/10.1107/S1600536809006035
Descripción
Sumario:The title compound, C(16)H(17)NOS(2), consists of a carbazole skeleton with tetra­hydro­furan and dithiol­ane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)°. The cyclo­hexenone and tetra­hydro­furan rings have envelope conformations, while the dithiol­ane ring adopts a twist conformation. In the crystal structure, pairs of weak inter­molecular N—H⋯S hydrogen bonds link the mol­ecules into centrosymmetric dimers with R (2) (2)(16) ring motifs. Weak C—H⋯π inter­actions may further stabilize the structure.