3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole

The title compound, C(16)H(17)NOS(2), consists of a carbazole skeleton with tetra­hydro­furan and dithiol­ane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)°. The cyclo­hexenone and tetra­hydro­furan rings have envelope conf...

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Detalles Bibliográficos
Autores principales: Uludağ, Nesimi, Öztürk, Aslı, Hökelek, Tuncer, Erdoğan, Ümit Işık
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968651/
https://www.ncbi.nlm.nih.gov/pubmed/21582250
http://dx.doi.org/10.1107/S1600536809006035
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author Uludağ, Nesimi
Öztürk, Aslı
Hökelek, Tuncer
Erdoğan, Ümit Işık
author_facet Uludağ, Nesimi
Öztürk, Aslı
Hökelek, Tuncer
Erdoğan, Ümit Işık
author_sort Uludağ, Nesimi
collection PubMed
description The title compound, C(16)H(17)NOS(2), consists of a carbazole skeleton with tetra­hydro­furan and dithiol­ane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)°. The cyclo­hexenone and tetra­hydro­furan rings have envelope conformations, while the dithiol­ane ring adopts a twist conformation. In the crystal structure, pairs of weak inter­molecular N—H⋯S hydrogen bonds link the mol­ecules into centrosymmetric dimers with R (2) (2)(16) ring motifs. Weak C—H⋯π inter­actions may further stabilize the structure.
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spelling pubmed-29686512010-12-30 3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole Uludağ, Nesimi Öztürk, Aslı Hökelek, Tuncer Erdoğan, Ümit Işık Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(17)NOS(2), consists of a carbazole skeleton with tetra­hydro­furan and dithiol­ane rings. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.57 (15)°. The cyclo­hexenone and tetra­hydro­furan rings have envelope conformations, while the dithiol­ane ring adopts a twist conformation. In the crystal structure, pairs of weak inter­molecular N—H⋯S hydrogen bonds link the mol­ecules into centrosymmetric dimers with R (2) (2)(16) ring motifs. Weak C—H⋯π inter­actions may further stabilize the structure. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968651/ /pubmed/21582250 http://dx.doi.org/10.1107/S1600536809006035 Text en © Uludağ et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Uludağ, Nesimi
Öztürk, Aslı
Hökelek, Tuncer
Erdoğan, Ümit Işık
3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole
title 3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole
title_full 3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole
title_fullStr 3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole
title_full_unstemmed 3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole
title_short 3,3-Ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2H-furo[2,3-a]carbazole
title_sort 3,3-ethyl­enedithio-3,3a,4,5,10,10b-hexa­hydro-2h-furo[2,3-a]carbazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968651/
https://www.ncbi.nlm.nih.gov/pubmed/21582250
http://dx.doi.org/10.1107/S1600536809006035
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AT ozturkaslı 33ethylenedithio33a451010bhexahydro2hfuro23acarbazole
AT hokelektuncer 33ethylenedithio33a451010bhexahydro2hfuro23acarbazole
AT erdoganumitisık 33ethylenedithio33a451010bhexahydro2hfuro23acarbazole

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