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Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8) O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride
The title compound (C(5)H(14)NO)(4)[Cu(2)(CH(3)COO)(4)Cl(2)]Cl(2), consists of a pair of Cu(II) ions bridged by four acetate groups, resulting in a Cu(2)(CH(3)COO)(4) unit, four (3-hydroxypropyl)dimethylammonium cations (two crystallographically independent pairs) and two chloride anions. The Cu...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968653/ https://www.ncbi.nlm.nih.gov/pubmed/21582111 http://dx.doi.org/10.1107/S160053680900662X |
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author | Shahid, Muhammad Mazhar, Muhammad Zeller, Matthias Hunter, Allen D. |
author_facet | Shahid, Muhammad Mazhar, Muhammad Zeller, Matthias Hunter, Allen D. |
author_sort | Shahid, Muhammad |
collection | PubMed |
description | The title compound (C(5)H(14)NO)(4)[Cu(2)(CH(3)COO)(4)Cl(2)]Cl(2), consists of a pair of Cu(II) ions bridged by four acetate groups, resulting in a Cu(2)(CH(3)COO)(4) unit, four (3-hydroxypropyl)dimethylammonium cations (two crystallographically independent pairs) and two chloride anions. The Cu atoms at both termini are bonded to chloride anions. The latter are hydrogen bonded to one of the two pairs of crystallographically independent (3-hydroxypropyl)dimethylammonium cations. The Cu(2)(CH(3)COO)(4) unit is located on a crystallographic inversion center, and the geometry around each metal center is close to octahedral. The Cl—Cu—Cu angles are nearly linear [177.48 (2)°] and the Cu—O bond lengths are in the range 1.9712 (18)–1.9809 (19) Å. The Cu⋯Cu separation between the two acetate-bridged Cu(II) centers is 2.6793 (8) Å. The packing of the crystal structure is dominated by N—H⋯Cl hydrogen bonding between the ammonium groups and the chloride anions, as well as by O—H⋯O and O—H⋯Cl hydrogen bonds. One of the 3-hydroxypropyldimethylammonium cations shows orientational disorder with an occupancy ratio of 0.812 (4): 0.188 (4). |
format | Text |
id | pubmed-2968653 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29686532010-12-30 Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8) O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride Shahid, Muhammad Mazhar, Muhammad Zeller, Matthias Hunter, Allen D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound (C(5)H(14)NO)(4)[Cu(2)(CH(3)COO)(4)Cl(2)]Cl(2), consists of a pair of Cu(II) ions bridged by four acetate groups, resulting in a Cu(2)(CH(3)COO)(4) unit, four (3-hydroxypropyl)dimethylammonium cations (two crystallographically independent pairs) and two chloride anions. The Cu atoms at both termini are bonded to chloride anions. The latter are hydrogen bonded to one of the two pairs of crystallographically independent (3-hydroxypropyl)dimethylammonium cations. The Cu(2)(CH(3)COO)(4) unit is located on a crystallographic inversion center, and the geometry around each metal center is close to octahedral. The Cl—Cu—Cu angles are nearly linear [177.48 (2)°] and the Cu—O bond lengths are in the range 1.9712 (18)–1.9809 (19) Å. The Cu⋯Cu separation between the two acetate-bridged Cu(II) centers is 2.6793 (8) Å. The packing of the crystal structure is dominated by N—H⋯Cl hydrogen bonding between the ammonium groups and the chloride anions, as well as by O—H⋯O and O—H⋯Cl hydrogen bonds. One of the 3-hydroxypropyldimethylammonium cations shows orientational disorder with an occupancy ratio of 0.812 (4): 0.188 (4). International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968653/ /pubmed/21582111 http://dx.doi.org/10.1107/S160053680900662X Text en © Shahid et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shahid, Muhammad Mazhar, Muhammad Zeller, Matthias Hunter, Allen D. Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8) O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride |
title | Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8)
O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride |
title_full | Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8)
O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride |
title_fullStr | Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8)
O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride |
title_full_unstemmed | Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8)
O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride |
title_short | Tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8)
O:O′-bis[chloridocuprate(II)](Cu—Cu) dichloride |
title_sort | tetrakis[(3-hydroxypropyl)dimethylammonium] tetra-μ-acetato-κ(8)
o:o′-bis[chloridocuprate(ii)](cu—cu) dichloride |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968653/ https://www.ncbi.nlm.nih.gov/pubmed/21582111 http://dx.doi.org/10.1107/S160053680900662X |
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