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Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride

The title compound (C(5)H(14)NO)(4)[Cu(2)(CH(3)COO)(4)Cl(2)]Cl(2), consists of a pair of Cu(II) ions bridged by four acetate groups, resulting in a Cu(2)(CH(3)COO)(4) unit, four (3-hydroxy­prop­yl)dimethyl­ammonium cations (two crystallographically independent pairs) and two chloride anions. The Cu...

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Autores principales: Shahid, Muhammad, Mazhar, Muhammad, Zeller, Matthias, Hunter, Allen D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968653/
https://www.ncbi.nlm.nih.gov/pubmed/21582111
http://dx.doi.org/10.1107/S160053680900662X
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author Shahid, Muhammad
Mazhar, Muhammad
Zeller, Matthias
Hunter, Allen D.
author_facet Shahid, Muhammad
Mazhar, Muhammad
Zeller, Matthias
Hunter, Allen D.
author_sort Shahid, Muhammad
collection PubMed
description The title compound (C(5)H(14)NO)(4)[Cu(2)(CH(3)COO)(4)Cl(2)]Cl(2), consists of a pair of Cu(II) ions bridged by four acetate groups, resulting in a Cu(2)(CH(3)COO)(4) unit, four (3-hydroxy­prop­yl)dimethyl­ammonium cations (two crystallographically independent pairs) and two chloride anions. The Cu atoms at both termini are bonded to chloride anions. The latter are hydrogen bonded to one of the two pairs of crystallographically independent (3-hydroxy­prop­yl)dimethyl­ammonium cations. The Cu(2)(CH(3)COO)(4) unit is located on a crystallographic inversion center, and the geometry around each metal center is close to octa­hedral. The Cl—Cu—Cu angles are nearly linear [177.48 (2)°] and the Cu—O bond lengths are in the range 1.9712 (18)–1.9809 (19) Å. The Cu⋯Cu separation between the two acetate-bridged Cu(II) centers is 2.6793 (8) Å. The packing of the crystal structure is dominated by N—H⋯Cl hydrogen bonding between the ammonium groups and the chloride anions, as well as by O—H⋯O and O—H⋯Cl hydrogen bonds. One of the 3-hydroxypropyldimethylammonium cations shows orientational disorder with an occupancy ratio of 0.812 (4): 0.188 (4).
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spelling pubmed-29686532010-12-30 Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride Shahid, Muhammad Mazhar, Muhammad Zeller, Matthias Hunter, Allen D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound (C(5)H(14)NO)(4)[Cu(2)(CH(3)COO)(4)Cl(2)]Cl(2), consists of a pair of Cu(II) ions bridged by four acetate groups, resulting in a Cu(2)(CH(3)COO)(4) unit, four (3-hydroxy­prop­yl)dimethyl­ammonium cations (two crystallographically independent pairs) and two chloride anions. The Cu atoms at both termini are bonded to chloride anions. The latter are hydrogen bonded to one of the two pairs of crystallographically independent (3-hydroxy­prop­yl)dimethyl­ammonium cations. The Cu(2)(CH(3)COO)(4) unit is located on a crystallographic inversion center, and the geometry around each metal center is close to octa­hedral. The Cl—Cu—Cu angles are nearly linear [177.48 (2)°] and the Cu—O bond lengths are in the range 1.9712 (18)–1.9809 (19) Å. The Cu⋯Cu separation between the two acetate-bridged Cu(II) centers is 2.6793 (8) Å. The packing of the crystal structure is dominated by N—H⋯Cl hydrogen bonding between the ammonium groups and the chloride anions, as well as by O—H⋯O and O—H⋯Cl hydrogen bonds. One of the 3-hydroxypropyldimethylammonium cations shows orientational disorder with an occupancy ratio of 0.812 (4): 0.188 (4). International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968653/ /pubmed/21582111 http://dx.doi.org/10.1107/S160053680900662X Text en © Shahid et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shahid, Muhammad
Mazhar, Muhammad
Zeller, Matthias
Hunter, Allen D.
Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride
title Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride
title_full Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride
title_fullStr Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride
title_full_unstemmed Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride
title_short Tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) O:O′-bis­[chloridocuprate(II)](Cu—Cu) dichloride
title_sort tetra­kis[(3-hydroxy­prop­yl)dimethyl­ammonium] tetra-μ-acetato-κ(8) o:o′-bis­[chloridocuprate(ii)](cu—cu) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968653/
https://www.ncbi.nlm.nih.gov/pubmed/21582111
http://dx.doi.org/10.1107/S160053680900662X
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