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catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]

In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octa­hedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridine­dicarboxyl­ate (PDA) ligand in a tridentate manner, one N atom of the pyridine mol­ecule...

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Detalles Bibliográficos
Autores principales: Trivedi, Manoj, Pandey, Daya Shankar, Rath, Nigam P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968654/
https://www.ncbi.nlm.nih.gov/pubmed/21582082
http://dx.doi.org/10.1107/S1600536809005212
Descripción
Sumario:In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octa­hedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridine­dicarboxyl­ate (PDA) ligand in a tridentate manner, one N atom of the pyridine mol­ecule and two bridging carboxyl­ate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C—H⋯O and π–π inter­actions into a three-dimensional supra­molecular network structure. The centroid–centroid distance between the π–π inter­acting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu.