Cargando…

catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]

In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octa­hedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridine­dicarboxyl­ate (PDA) ligand in a tridentate manner, one N atom of the pyridine mol­ecule...

Descripción completa

Detalles Bibliográficos
Autores principales: Trivedi, Manoj, Pandey, Daya Shankar, Rath, Nigam P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968654/
https://www.ncbi.nlm.nih.gov/pubmed/21582082
http://dx.doi.org/10.1107/S1600536809005212
_version_ 1782189944570118144
author Trivedi, Manoj
Pandey, Daya Shankar
Rath, Nigam P.
author_facet Trivedi, Manoj
Pandey, Daya Shankar
Rath, Nigam P.
author_sort Trivedi, Manoj
collection PubMed
description In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octa­hedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridine­dicarboxyl­ate (PDA) ligand in a tridentate manner, one N atom of the pyridine mol­ecule and two bridging carboxyl­ate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C—H⋯O and π–π inter­actions into a three-dimensional supra­molecular network structure. The centroid–centroid distance between the π–π inter­acting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu.
format Text
id pubmed-2968654
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29686542010-12-30 catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)] Trivedi, Manoj Pandey, Daya Shankar Rath, Nigam P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octa­hedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridine­dicarboxyl­ate (PDA) ligand in a tridentate manner, one N atom of the pyridine mol­ecule and two bridging carboxyl­ate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C—H⋯O and π–π inter­actions into a three-dimensional supra­molecular network structure. The centroid–centroid distance between the π–π inter­acting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968654/ /pubmed/21582082 http://dx.doi.org/10.1107/S1600536809005212 Text en © Trivedi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Trivedi, Manoj
Pandey, Daya Shankar
Rath, Nigam P.
catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]
title catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]
title_full catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]
title_fullStr catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]
title_full_unstemmed catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]
title_short catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]
title_sort catena-poly[[(pyridine-κn)copper(ii)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) o (2):o (2′),n,o (6):o (6′)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968654/
https://www.ncbi.nlm.nih.gov/pubmed/21582082
http://dx.doi.org/10.1107/S1600536809005212
work_keys_str_mv AT trivedimanoj catenapolypyridinekncopperiim3pyridine26dicarboxylatok3o2o2no6o6
AT pandeydayashankar catenapolypyridinekncopperiim3pyridine26dicarboxylatok3o2o2no6o6
AT rathnigamp catenapolypyridinekncopperiim3pyridine26dicarboxylatok3o2o2no6o6