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catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)]
In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octahedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridinedicarboxylate (PDA) ligand in a tridentate manner, one N atom of the pyridine molecule...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968654/ https://www.ncbi.nlm.nih.gov/pubmed/21582082 http://dx.doi.org/10.1107/S1600536809005212 |
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author | Trivedi, Manoj Pandey, Daya Shankar Rath, Nigam P. |
author_facet | Trivedi, Manoj Pandey, Daya Shankar Rath, Nigam P. |
author_sort | Trivedi, Manoj |
collection | PubMed |
description | In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octahedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridinedicarboxylate (PDA) ligand in a tridentate manner, one N atom of the pyridine molecule and two bridging carboxylate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C—H⋯O and π–π interactions into a three-dimensional supramolecular network structure. The centroid–centroid distance between the π–π interacting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu. |
format | Text |
id | pubmed-2968654 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29686542010-12-30 catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)] Trivedi, Manoj Pandey, Daya Shankar Rath, Nigam P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(3)NO(4))(C(5)H(5)N)](n), the Cu(II) atom is in a slightly distorted octahedral coordination environment. Each Cu(II) atom is bound to two N atoms and one O atom of the pyridinedicarboxylate (PDA) ligand in a tridentate manner, one N atom of the pyridine molecule and two bridging carboxylate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C—H⋯O and π–π interactions into a three-dimensional supramolecular network structure. The centroid–centroid distance between the π–π interacting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968654/ /pubmed/21582082 http://dx.doi.org/10.1107/S1600536809005212 Text en © Trivedi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Trivedi, Manoj Pandey, Daya Shankar Rath, Nigam P. catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3) O (2):O (2′),N,O (6):O (6′)] |
title |
catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3)
O
(2):O
(2′),N,O
(6):O
(6′)] |
title_full |
catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3)
O
(2):O
(2′),N,O
(6):O
(6′)] |
title_fullStr |
catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3)
O
(2):O
(2′),N,O
(6):O
(6′)] |
title_full_unstemmed |
catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3)
O
(2):O
(2′),N,O
(6):O
(6′)] |
title_short |
catena-Poly[[(pyridine-κN)copper(II)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3)
O
(2):O
(2′),N,O
(6):O
(6′)] |
title_sort | catena-poly[[(pyridine-κn)copper(ii)]-μ(3)-pyridine-2,6-dicarboxylato-κ(3)
o
(2):o
(2′),n,o
(6):o
(6′)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968654/ https://www.ncbi.nlm.nih.gov/pubmed/21582082 http://dx.doi.org/10.1107/S1600536809005212 |
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